1 -(Ethenyloxy)-butane

Base Information

• Chemical Name: 1 -(Ethenyloxy)-butane
• CAS No.: 111-34-2
• Molecular Formula: C6H12O
• Molecular Weight: 100.161
• Hs Code.: 2909199090
• European Community (EC) Number: 203-860-7
• NSC Number: 8264
• UN Number: 2352
• UNII: 321YRT7173
• DSSTox Substance ID: DTXSID5051575
• Nikkaji Number: J75.043C
• Wikidata: Q1018214
• Metabolomics Workbench ID: 132017
• ChEMBL ID: CHEMBL3561125
• Mol file: 111-34-2.mol

Synonyms:n-Butyl vinyl ether;Ether,butyl vinyl (8CI);1-(Ethenyloxy)butane;1-(Vinyloxy)butane;1-Butoxyethene;BVE;Butoxyethene;Butoxyethylene;Butane, 1-(ethenyloxy)-;NBVE;NSC 8264;Vinylbutyl ether;Vinyl n-butyl ether;

Chemical Property of 1 -(Ethenyloxy)-butane

Chemical Property:

• Appearance/Colour: clear liquid
• Vapor Pressure: 55.8mmHg at 25°C
• Melting Point: -92 °C(lit.)
• Refractive Index: 1.4026
• Boiling Point: 93.6 °C at 760 mmHg
• Flash Point: 15°F
• PSA: 9.23000
• Density: 0.776 g/cm³
• LogP: 1.94660
• Water Solubility.: 3 g/L (20℃)
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 100.088815002
• Heavy Atom Count: 7
• Complexity: 41.4
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F:Flammable
• Statements: R11:; R19:
• Safety Statements: S16:; S33:; S9:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> Other Monomers
• Canonical SMILES: CCCCOC=C

Technology Process of 1 -(Ethenyloxy)-butane

There total 29 articles about 1 -(Ethenyloxy)-butane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

dibutyl acetal (871-22-7) + 6,6-Dimethyloenanthsaeure (15898-92-7) → -butyl vinyl ether (111-34-2,92680-80-3)

Guidance literature:

Reference yield: 82.0%

acetylene (74-86-2,25067-58-7) + butan-1-ol (71-36-3) → -butyl vinyl ether (111-34-2,92680-80-3)

Guidance literature:

With sodium hydroxide; cesium fluoride; at 135 - 140 ℃; for 3h; under 7600 - 10640 Torr;

DOI:10.1007/s11178-005-0222-y

Reference yield: 68.0%

(2-butoxy-ethanesulfinyl)-ethene (81577-06-2) → -butyl vinyl ether (111-34-2,92680-80-3) + ethenesulfenic acid (2492-74-2)

Guidance literature:

With potassium hydroxide; at 280 - 290 ℃;

upstream raw materials:

butane, 1-(1-ethoxyethoxy)-

dibutyl acetal

1,1-dibutoxy-2-chloro-ethane

1-chloro-hexan-3-ol

Downstream raw materials:

N-vinyl-2-oxazolidone

1,1-bis-(2-phenyl-acetylamino)-ethane

allyl vinyl ether

dibutyl acetal

Refernces

• 1、 Rodygin, Konstantin S.,Lotsman, Kristina A.,Ananikov, Valentine P.. "Calcium Carbide Looping System for Acetaldehyde Manufacturing from Virtually any Carbon Source". . p. 3679 - 3685. Retrieved 2020/06/17.
• 2、 Oparina,Shaikhudinova,Parshina,Vysotskaya,Preiss,Henkelmann,Trofimov. "Nucleophilic addition to acetylenes in superbasic catalytic systems: XIII. Fluoride cesium containing systems, efficient catalysts for alkanols vinylation". . p. 656 - 660. Retrieved 2007/10/03.