CAS No.111-34-2,1 -(Ethenyloxy)-butane Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	111-34-2
Name:	1 -(Ethenyloxy)-butane
Article Data:	48
Cas Database

Formula:	C₆H₁₂O
Molecular Weight:	100.161
Synonyms:	n-Butyl vinyl ether;Ether,butyl vinyl (8CI);1-(Ethenyloxy)butane;1-(Vinyloxy)butane;1-Butoxyethene;BVE;Butoxyethene;Butoxyethylene;Butane, 1-(ethenyloxy)-;NBVE;NSC 8264;Vinylbutyl ether;Vinyl n-butyl ether;
EINECS:	203-860-7
Density:	0.776 g/cm³
Melting Point:	-92 °C(lit.)
Boiling Point:	93.6 °C at 760 mmHg
Flash Point:	15°F
Solubility:	3 g/L (20 °C) in water
Appearance:	clear liquid
Hazard Symbols:	F
Risk Codes:	11-19
Safety:	9-14-16-33
Transport Information:	UN 2352 3/PG 2
PSA:	9.23000
LogP:	1.94660

Synthetic route

: 871-22-7
dibutyl acetal

: 15898-92-7
6,6-Dimethyloenanthsaeure

: 111-34-2
-butyl vinyl ether

Conditions

Conditions	Yield
	83%

: 74-86-2
acetylene

: 71-36-3
butan-1-ol

: 111-34-2
-butyl vinyl ether

Conditions

Conditions	Yield
With sodium hydroxide; cesium fluoride at 135 - 140℃; under 7600 - 10640 Torr; for 3h;	82%
With sodium butanolate at 100 - 150℃;
With potassium n-butoxide; paraffin oil at 180 - 190℃;

: 81577-06-2
(2-butoxy-ethanesulfinyl)-ethene

A: 111-34-2
-butyl vinyl ether

B: 2492-74-2
ethenesulfenic acid

Conditions

Conditions	Yield
With potassium hydroxide at 280 - 290℃;	A 68% B n/a

: 1112-54-5
vinyltriethylsilane

: 71-36-3
butan-1-ol

A: 111-34-2
-butyl vinyl ether

B: 994-49-0
hexaethyl disiloxane

Conditions

Conditions	Yield
With bromine for 4h;	A 65% B 20%

...Expand

: 871-22-7
dibutyl acetal

A: 111-34-2
-butyl vinyl ether

B: 71-36-3
butan-1-ol

Conditions

Conditions	Yield
phosphoric acid at 200℃; Product distribution; various catalysts;	A 12.5% B 16.7%

: 57006-87-8
butane, 1-(1-ethoxyethoxy)-

: 111-34-2
-butyl vinyl ether

Conditions

Conditions	Yield
at 300℃; beim Leiten ueber Kaolin;

: 871-22-7
dibutyl acetal

: 111-34-2
-butyl vinyl ether

Conditions

Conditions	Yield
With sodium hydrogen sulfate
With phosphoric acid
With palladium asbestos at 300℃;
With boric acid asbestos at 380 - 410℃;

: 17437-27-3
1,1-dibutoxy-2-chloro-ethane

: 111-34-2
-butyl vinyl ether

Conditions

Conditions	Yield
With sodium at 150℃;

: 52418-81-2
1-chloro-hexan-3-ol

A: 111-34-2
-butyl vinyl ether

B: 112-73-2
diethylene glycol dibutyl ether

Conditions

Conditions	Yield
With sodium hydroxide

: 75-01-4
chloroethylene

: 2372-45-4
sodium butanolate

: 111-34-2
-butyl vinyl ether

Conditions

Conditions	Yield
at 100℃;

Raw Materials

3999-70-0

74-86-2

71-43-2

75-01-4

111-76-2

3450-47-3

71-36-3

7175-49-7

Downstream Products

88-12-0

1736-67-0

100-19-6

2050-68-2

586-37-8

4157-77-1

628-81-9

75-07-0

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Chemistry

Structure of n-Butylvinylether (CAS NO.111-34-2):

IUPAC Name: 1-ethenoxybutane
Empirical Formula: C₆H₁₂O
Molecular Weight: 100.1589
EINECS: 203-860-7
Index of Refraction: 1.4
Molar Refractivity: 31.31 cm³
Molar Volume: 129 cm³
Polarizability: 12.41×10^-24cm³
Surface Tension: 22 dyne/cm
Density: 0.776 g/cm³
Enthalpy of Vaporization: 31.58 kJ/mol
Melting Point: −92 °C(lit.)
Boiling Point: 93.6 °C at 760 mmHg
Vapour Pressure: 55.8 mmHg at 25°C
Water Solubility: 3 g/L (20 ºC)
Physical Appearance: clear liquid
Synonyms of n-Butylvinylether (CAS NO.111-34-2): Butane, 1-(ethenyloxy)- ; Butil vinil eter ; Butoxyethene ; Butoxyethylene ; Ethenyl n-butyl ether ; Ether butylvinylique ; Ether, butyl vinyl ; Vinyl butyl ether ; Vinyl n-butyl ether ; n-n-Butylvinylether

Toxicity Data With Reference

1.	skn-rbt 500 mg open MLD	UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 6/28 ,1973.
2.	eye-rbt 500 mg open	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.	orl-rat LD50:10 g/kg	UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 6/28 ,1972.
4.	ihl-uns LC50:60 g/m3	GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 32 (10)(1988),25.
5.	ihl-mus LC50:62 g/m3/2H	85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,119.
6.	skn-rbt LD50:4240 mg/kg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: F
Risk Statements: 11-19
R11:Highly flammable.
R19:May form explosive peroxides.
Safety Statements: 9-14-16-33
S9:Keep container in a well-ventilated place.
S14:Keep away from ... (a list of incompatible materials will follow).
S16:Keep away from sources of ignition.
S33:Take precautionary measures against static discharges.
RIDADR: UN 2352 3/PG 2
WGK Germany: 2
RTECS: KN5950000
HazardClass: 3
PackingGroup: II
Mildly toxic by ingestion, skin contact, and inhalation. A skin and eye irritant. A very dangerous fire hazard when exposed to HEAT or flame. To fight fire, use foam, CO₂, dry chemical, alcohol foam. Moderately explosive by spontaneous chemical reaction. Can react with oxidizing materials. When HEATed to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.

Standards and Recommendations

DOT Classification: 3; Label: Flammable Liquid