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Basic Information
CAS No.: 111-34-2
Name: 1 -(Ethenyloxy)-butane
Article Data: 48
Molecular Structure:
Molecular Structure of 111-34-2 (1 -(Ethenyloxy)-butane)
Formula: C6H12O
Molecular Weight: 100.161
Synonyms: n-Butyl vinyl ether;Ether,butyl vinyl (8CI);1-(Ethenyloxy)butane;1-(Vinyloxy)butane;1-Butoxyethene;BVE;Butoxyethene;Butoxyethylene;Butane, 1-(ethenyloxy)-;NBVE;NSC 8264;Vinylbutyl ether;Vinyl n-butyl ether;
EINECS: 203-860-7
Density: 0.776 g/cm3
Melting Point: -92 °C(lit.)
Boiling Point: 93.6 °C at 760 mmHg
Flash Point: 15°F
Solubility: 3 g/L (20 °C) in water
Appearance: clear liquid
Hazard Symbols: FlammableF
Risk Codes: 11-19
Safety: 9-14-16-33
Transport Information: UN 2352 3/PG 2
PSA: 9.23000
LogP: 1.94660
Synthetic route
871-22-7

dibutyl acetal

15898-92-7

6,6-Dimethyloenanthsaeure

111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
83%
74-86-2

acetylene

71-36-3

butan-1-ol

111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With sodium hydroxide; cesium fluoride at 135 - 140℃; under 7600 - 10640 Torr; for 3h;82%
With sodium butanolate at 100 - 150℃;
With potassium n-butoxide; paraffin oil at 180 - 190℃;
81577-06-2

(2-butoxy-ethanesulfinyl)-ethene

A

111-34-2

-butyl vinyl ether

B

2492-74-2

ethenesulfenic acid

Conditions
ConditionsYield
With potassium hydroxide at 280 - 290℃;A 68%
B n/a
1112-54-5

vinyltriethylsilane

71-36-3

butan-1-ol

A

111-34-2

-butyl vinyl ether

B

994-49-0

hexaethyl disiloxane

Conditions
ConditionsYield
With bromine for 4h;A 65%
B 20%
871-22-7

dibutyl acetal

A

111-34-2

-butyl vinyl ether

B

71-36-3

butan-1-ol

Conditions
ConditionsYield
phosphoric acid at 200℃; Product distribution; various catalysts;A 12.5%
B 16.7%
57006-87-8

butane, 1-(1-ethoxyethoxy)-

111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
at 300℃; beim Leiten ueber Kaolin;
871-22-7

dibutyl acetal

111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With sodium hydrogen sulfate
With phosphoric acid
With palladium asbestos at 300℃;
With boric acid asbestos at 380 - 410℃;
17437-27-3

1,1-dibutoxy-2-chloro-ethane

111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With sodium at 150℃;
52418-81-2

1-chloro-hexan-3-ol

A

111-34-2

-butyl vinyl ether

B

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With sodium hydroxide
75-01-4

chloroethylene

2372-45-4

sodium butanolate

111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
at 100℃;
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Chemistry

Structure of n-Butylvinylether (CAS NO.111-34-2):

IUPAC Name: 1-ethenoxybutane 
Empirical Formula: C6H12O
Molecular Weight: 100.1589 
EINECS: 203-860-7 
Index of Refraction: 1.4
Molar Refractivity: 31.31 cm3
Molar Volume: 129 cm3
Polarizability: 12.41×10-24cm3
Surface Tension: 22 dyne/cm
Density: 0.776 g/cm3
Enthalpy of Vaporization: 31.58 kJ/mol 
Melting Point: −92 °C(lit.)
Boiling Point: 93.6 °C at 760 mmHg
Vapour Pressure: 55.8 mmHg at 25°C 
Water Solubility: 3 g/L (20 ºC) 
Physical Appearance: clear liquid
Synonyms of n-Butylvinylether (CAS NO.111-34-2): Butane, 1-(ethenyloxy)- ; Butil vinil eter ; Butoxyethene ; Butoxyethylene ; Ethenyl n-butyl ether ; Ether butylvinylique ; Ether, butyl vinyl ; Vinyl butyl ether ; Vinyl n-butyl ether ; n-n-Butylvinylether 

Toxicity Data With Reference

1.    

skn-rbt 500 mg open MLD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 6/28 ,1973.
2.    

eye-rbt 500 mg open

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.    

orl-rat LD50:10 g/kg

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 6/28 ,1972.
4.    

ihl-uns LC50:60 g/m3

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 32 (10)(1988),25.
5.    

ihl-mus LC50:62 g/m3/2H

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,119.
6.    

skn-rbt LD50:4240 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: FlammableF
Risk Statements: 11-19 
R11:Highly flammable. 
R19:May form explosive peroxides.
Safety Statements: 9-14-16-33 
S9:Keep container in a well-ventilated place. 
S14:Keep away from ... (a list of incompatible materials will follow). 
S16:Keep away from sources of ignition. 
S33:Take precautionary measures against static discharges.
RIDADR: UN 2352 3/PG 2
WGK Germany: 2
RTECS: KN5950000
HazardClass: 3
PackingGroup: II
Mildly toxic by ingestion, skin contact, and inhalation. A skin and eye irritant. A very dangerous fire hazard when exposed to HEAT or flame. To fight fire, use foam, CO2, dry chemical, alcohol foam. Moderately explosive by spontaneous chemical reaction. Can react with oxidizing materials. When HEATed to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.

Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid