N-Phenyl-3-biphenylamine

Base Information

• Chemical Name: N-Phenyl-3-biphenylamine
• CAS No.: 198275-79-5
• Molecular Formula: C18H15N
• Molecular Weight: 245.324
• Hs Code.: 2921499090
• Mol file: 198275-79-5.mol

Synonyms:3-ANILINOBIPHENYL;N-PHENYL-3-BIPHENYLAMINE;N-(1,1-Biphenyl-3-yl)-N-phenylamine;N-Phenyl-[1,1-biphenyl]-3-amine

Chemical Property of N-Phenyl-3-biphenylamine

Chemical Property:

• Vapor Pressure: 3.46E-07mmHg at 25°C
• Melting Point: 92 °C
• Boiling Point: 417.7°C at 760 mmHg
• Flash Point: 222.6°C
• PSA: 12.03000
• Density: 1.111g/cm³
• LogP: 5.17020
• Solubility.: soluble in Toluene

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-Phenyl-3-biphenylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-Phenyl-3-biphenylamine

There total 7 articles about N-Phenyl-3-biphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3-bromobiphenyl (2113-57-7) + aniline (62-53-3) → N-phenyl-[1,1′-biphenyl]-3-amine (198275-79-5)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In toluene; for 2h; Inert atmosphere; Reflux;

DOI:10.1016/j.poly.2012.06.078

Reference yield: 89.3%

→ N-phenyl-[1,1′-biphenyl]-3-amine (198275-79-5)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium tertiary butoxide; dicyclohexyl(2’,4’,6’-triisopropyl-[ 1,1’-bi-phenyl]-2-yl)phosphane; In toluene; at 65 - 75 ℃; for 1h; Inert atmosphere;

Reference yield: 81.0%

3-phenylcyclohex-2-enone (10345-87-6) + aniline (62-53-3) → N-phenyl-[1,1′-biphenyl]-3-amine (198275-79-5)

Guidance literature:

With hydrogenchloride; iodine; dimethyl sulfoxide; In N,N,N,N,N,N-hexamethylphosphoric triamide; water; at 110 ℃; for 20h; Schlenk technique; Sealed tube; Green chemistry;

DOI:10.1039/c8cc05320k

upstream raw materials:

bromobenzene

3-biphenyl amine

aniline

[1,1′-biphenyl]-3-yl trifluoromethanesulfonate

Downstream raw materials:

2-phenyl-10H-phenothiazine

N-([1,1'-biphenyl]-3-yl)-N-phenyl-[2,2'-bipyridin]-6-amine

C₂₈H₂₀ClN₃Pt

N-([1,1'-biphenyl]-3-yl)-6-bromo-N-phenylpyridin-2-amine

Refernces

• 1、 -. "Organic compound and electronic component and electronic device comprising same". Paragraph 0113-0115; 0116-0118; 0119. . Retrieved 2021/07/17.
• 2、 -. "Organic electroluminescent device and aromatic amine compound for same". Paragraph 0074-0075; 0077. . Retrieved 2019/04/17.