2-phenyl-9H-carbazole

Base Information

• Chemical Name: 2-phenyl-9H-carbazole
• CAS No.: 88590-00-5
• Molecular Formula: C18H13N
• Molecular Weight: 243.308
• Hs Code.: 2933998090
• Mol file: 88590-00-5.mol

Synonyms:2-phenyl-9H-carbazole;2-phenylcarbazole

Chemical Property of 2-phenyl-9H-carbazole

Chemical Property:

• Melting Point: 290 °C
• Boiling Point: 474.3±14.0 °C(Predicted)
• PKA: 16.87±0.30(Predicted)
• PSA: 15.79000
• Density: 1.208±0.06 g/cm3(Predicted)
• LogP: 4.98810
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

2-Phenyl-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-phenyl-9H-carbazole

There total 31 articles about 2-phenyl-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2-bromo-9H-carbazole (3652-90-2) + phenylboronic acid (98-80-6) → 2-phenyl-9H-carbazole (88590-00-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In ethanol; toluene; at 120 ℃; for 5h;

Reference yield: 93.0%

4-phenyl-2-nitro-1,1′-biphenyl (60366-15-6) → 2-phenyl-9H-carbazole (88590-00-5)

Guidance literature:

With iron; triphenylphosphine; In toluene; at 106 ℃; for 10h;

Reference yield: 90.0%

2-nitrophenyl bromide (577-19-5) + 4-biphenylboronic acid (5122-94-1) → 2-phenyl-9H-carbazole (88590-00-5)

Guidance literature:

With palladium diacetate; potassium carbonate; triphenylphosphine; In 1,2-dichloro-benzene; at 180 ℃; for 24h;

DOI:10.1039/c5ob01952d

upstream raw materials:

1,4-dibromo-2-nitrobenzene

phenylboronic acid

N-phenyl-[1,1′-biphenyl]-3-amine

4-(4-bromophenyl)bromobenzene

Refernces

• 1、 Steingruber, H. Sebastián,Mendioroz, Pamela,Volpe, María A.,Gerbino, Darío C.. "Convenient One-Pot Synthesis of 9 H -Carbazoles by Microwave Irradiation Employing a Green Palladium-Based Nanocatalyst". . p. 4048 - 4058. Retrieved 2021/08/03.
• 2、 -. "ORGANIC OPTOELECTRONIC DEVICE AND DISPLAY DEVICE". Paragraph 0298-0300. . Retrieved 2020/05/29.