3-(Bromomethyl)-1,1-dimethylcyclobutane

Base Information

• Chemical Name: 3-(Bromomethyl)-1,1-dimethylcyclobutane
• CAS No.: 76207-22-2
• Molecular Formula: C7H13Br
• Molecular Weight: 177.084
• Hs Code.: 2903898090
• Mol file: 76207-22-2.mol

Synonyms:F2147-1654;A9659;

Chemical Property of 3-(Bromomethyl)-1,1-dimethylcyclobutane

Chemical Property:

• Vapor Pressure: 9.127mmHg at 25°C
• Boiling Point: 136.46°C at 760 mmHg
• Flash Point: 32.651°C
• PSA: 0.00000
• Density: 1.233g/cm³
• LogP: 2.81750

Purity/Quality:

97% ^*data from raw suppliers

3-(bromomethyl)-1,1-dimethylcyclobutane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-(Bromomethyl)-1,1-dimethylcyclobutane

There total 3 articles about 3-(Bromomethyl)-1,1-dimethylcyclobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(3,3-dimethylcyclobutyl)methyl-4-methylbenzene-1-sulfonate (76207-24-4) → 1,2-dimethyl-3-(bromomethyl)cyclobutane (76207-22-2)

Guidance literature:

With lithium bromide; In acetone; Ambient temperature;

DOI:10.1021/jo00319a026

Reference yield:

3,3-dimethylcyclobutanecarboxylic acid (34970-18-8) → 1,2-dimethyl-3-(bromomethyl)cyclobutane (76207-22-2)

Guidance literature:

Multi-step reaction with 3 steps

1: lithium aluminium hydride

2: pyridine / 2 h / Ambient temperature

3: lithium bromide / acetone / Ambient temperature

With lithium aluminium tetrahydride; lithium bromide; In pyridine; acetone;

DOI:10.1021/jo00319a026

Reference yield:

(3,3-dimethylcyclobutyl)methanol (75017-17-3) → 1,2-dimethyl-3-(bromomethyl)cyclobutane (76207-22-2)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / 2 h / Ambient temperature

2: lithium bromide / acetone / Ambient temperature

With lithium bromide; In pyridine; acetone;

DOI:10.1021/jo00319a026

upstream raw materials:

(3,3-dimethylcyclobutyl)methyl-4-methylbenzene-1-sulfonate

3,3-dimethylcyclobutanecarboxylic acid

(3,3-dimethylcyclobutyl)methanol

Downstream raw materials:

4,4-dimethylpent-1-ene

1,1,3-trimethylcyclobutane

C₁₄H₂₆

C₇H₁₃BrMg