2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-(TERT-BUTOXYCARBONYL)-1,5-DEOXY-1,5-IMINO-D-GLUCITOL

Base Information

Chemical Name:2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-(TERT-BUTOXYCARBONYL)-1,5-DEOXY-1,5-IMINO-D-GLUCITOL
CAS No.:133697-22-0
Molecular Formula:C18H23NO5
Molecular Weight:333.38
Hs Code.:
Mol file:133697-22-0.mol

Synonyms:2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-(TERT-BUTOXYCARBONYL)-1,5-DEOXY-1,5-IMINO-D-GLUCITOL;[2R-(2α,4aα,6aβ,7aβ,7bβ)]-Hexahydro-2-phenyl-5H-1,3-dioxino[5,4-b]oxireno[d]pyridine-5-carboxylic Acid 1,1-DiMethylethyl Ester

Suppliers and Price of 2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-(TERT-BUTOXYCARBONYL)-1,5-DEOXY-1,5-IMINO-D-GLUCITOL

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol
10mg
$ 285.00

Medical Isotopes, Inc.
2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol
25 mg
$ 1880.00

Medical Isotopes, Inc.
2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol
5 mg
$ 860.00

Biosynth Carbosynth
2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol
5 mg
$ 272.60

Biosynth Carbosynth
2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol
2 mg
$ 149.90

Biosynth Carbosynth
2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol
50 mg
$ 1638.00

Biosynth Carbosynth
2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol
25 mg
$ 901.00

Biosynth Carbosynth
2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol
10 mg
$ 495.50

American Custom Chemicals Corporation
2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-BOC-1,5-DEOXY-1,5-IMINO-D-GLUCITOL 95.00%
50MG
$ 1963.50

American Custom Chemicals Corporation
2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-BOC-1,5-DEOXY-1,5-IMINO-D-GLUCITOL 95.00%
5MG
$ 786.50

Total 9 raw suppliers

Chemical Property of 2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-(TERT-BUTOXYCARBONYL)-1,5-DEOXY-1,5-IMINO-D-GLUCITOL

Chemical Property:

Appearance/Colour:White solid
Melting Point:130-131.5 °C
Boiling Point:456.616 °C at 760 mmHg
PKA:-1.33±0.40(Predicted)
Flash Point:229.954 °C
PSA：60.53000
Density:1.222 g/cm³
LogP:2.42520
Storage Temp.:-20?C Freezer
Solubility.:Chloroform, Ethyl Acetate, Methanol

Purity/Quality:

99% ^*data from raw suppliers

2,3-Anhydro-4,6-O-benzylidene-N-(tert-butoxycarbonyl)-1,5-deoxy-1,5-imino-D-glucitol ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-(TERT-BUTOXYCARBONYL)-1,5-DEOXY-1,5-IMINO-D-GLUCITOL

There total 6 articles about 2,3-ANHYDRO-4,6-O-BENZYLIDENE-N-(TERT-BUTOXYCARBONYL)-1,5-DEOXY-1,5-IMINO-D-GLUCITOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 24424-99-5
di-tert-butyl dicarbonate

: 160711-08-0
2,3-Anhydro-4,6-O-(R-benzylidene)-1,5-dideoxy-1,5-imino-D-mannitol

: 133697-21-9,133697-22-0
2,3-Anhydro-4,6-O-(R-benzylidene)-N-(tert-butoxycarbonyl)-1,5-dideoxy-1,5-imino-D-mannitol

Guidance literature:: With pyridine; for 92h; Ambient temperature;

Reference yield:

: 130539-12-7
N-Benzyloxycarbonyl-1,5-dideoxy-1,5-imino-D-glucitol

: 133697-21-9,133697-22-0
2,3-Anhydro-4,6-O-(R-benzylidene)-N-(tert-butoxycarbonyl)-1,5-dideoxy-1,5-imino-D-mannitol

Guidance literature:: Multi-step reaction with 5 steps

1: 54 percent / p-toluenesulfonic acid / dimethylformamide / 4 h / 60 - 65 °C

2: 1.) di-n-butyltin oxide, 2.) triethylamine / 1.) MeOH, reflux, 2 h, 2.) CH₂Cl₂, 0 deg C, 30 min; 20 deg C, 3 h

3: 75 percent / NaH / tetrahydrofuran / 18 h / 25 °C

4: 85 percent / H₂ / 4percent Pd/C / tetrahydrofuran / 5 h / 103.4 Torr

5: 76 percent / pyridine / 92 h / Ambient temperature

With pyridine; hydrogen; sodium hydride; di(n-butyl)tin oxide; toluene-4-sulfonic acid; triethylamine; palladium on activated charcoal; In tetrahydrofuran; N,N-dimethyl-formamide;

Reference yield:

: 19130-96-2
1,5-dideoxy-1,5-imino-D-glucitol

: 133697-21-9,133697-22-0
2,3-Anhydro-4,6-O-(R-benzylidene)-N-(tert-butoxycarbonyl)-1,5-dideoxy-1,5-imino-D-mannitol

Guidance literature:: Multi-step reaction with 6 steps

1: 54 percent / aq. NaHCO₃ / 18 h / Ambient temperature

2: 54 percent / p-toluenesulfonic acid / dimethylformamide / 4 h / 60 - 65 °C

3: 1.) di-n-butyltin oxide, 2.) triethylamine / 1.) MeOH, reflux, 2 h, 2.) CH₂Cl₂, 0 deg C, 30 min; 20 deg C, 3 h

4: 75 percent / NaH / tetrahydrofuran / 18 h / 25 °C

5: 85 percent / H₂ / 4percent Pd/C / tetrahydrofuran / 5 h / 103.4 Torr

6: 76 percent / pyridine / 92 h / Ambient temperature

With pyridine; hydrogen; sodium hydride; di(n-butyl)tin oxide; sodium hydrogencarbonate; toluene-4-sulfonic acid; triethylamine; palladium on activated charcoal; In tetrahydrofuran; N,N-dimethyl-formamide;