1-Decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Base Information

• Chemical Name: 1-Decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
• CAS No.: 433337-23-6
• Molecular Formula: C14H27N2.C2F6NO4S2
• Molecular Weight: 503.52
• European Community (EC) Number: 801-469-1
• ChEMBL ID: CHEMBL3188796
• DSSTox Substance ID: DTXSID4047913
• Mol file: 433337-23-6.mol

Synonyms:433337-23-6;1-Decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide;1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide;1-Decyl-3-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide;DTXSID4047913;MFCD12022376;bis((trifluoromethyl)sulfonyl)imide;bis(trifluoromethylsulfonyl)azanide;1-decyl-3-methylimidazol-3-ium;CHEMBL3188796;DTXCID7027889;Tox21_200590;NCGC00248750-01;NCGC00258144-01;BS-28670;SY056021;CAS-433337-23-6;CS-0186334;D4351;D80287;A913680;1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide;1-methyl-3-decylimidazolium bis(trifluoromethanesulfonyl)imide;1-Decyl-3-methyl-1H-imidazol-3-iumbis((trifluoromethyl)sulfonyl)amide

Chemical Property of 1-Decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Chemical Property:

• Refractive Index: 1.43658 (20 o)
• Boiling Point: 726.6 °C
• PSA: 93.85000
• Density: 1.2828 (20 oC)
• LogP: 6.67420
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 11
• Exact Mass: 503.13471767
• Heavy Atom Count: 31
• Complexity: 533

Purity/Quality:

99.9% ^*data from raw suppliers

1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCN1C=C[N+](=C1)C.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F
• Uses: 1-Decyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide is an organic, ionic liquid solvent used in various reactions, such as those with molybdenum(II) complexes with α-?diimines, where it helps control chemoselectivity.

Technology Process of 1-Decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

There total 7 articles about 1-Decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

bis(trifluoromethane)sulfonimide lithium (90076-65-6) + 1-methyl-3-decylimidazolium bromide (188589-32-4) → 1-decyl-3-methylimidazolium bis-trifluormethanesulfonimide (433337-23-6)

Guidance literature:

In dichloromethane; water; Kinetics;

DOI:10.1002/anie.201206113

Reference yield:

bis(trifluoromethane)sulfonimide lithium (90076-65-6) + 1-decyl-3-methylimidazol-3-ium chloride → 1-decyl-3-methylimidazolium bis-trifluormethanesulfonimide (433337-23-6)

Guidance literature:

In water;

DOI:10.1007/s11426-012-4663-1

Reference yield:

decyl chloride (1002-69-3) → 1-decyl-3-methylimidazolium bis-trifluormethanesulfonimide (433337-23-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 72 h / 69.99 °C / Inert atmosphere; Cooling

2: water / 0.25 h

In water;

DOI:10.1021/acs.jced.7b00242

upstream raw materials:

1-methyl-1H-imidazole

1-bromo dodecane

bis(trifluoromethane)sulfonimide lithium

1-methyl-3-decylimidazolium bromide