MeO-TPD, N,N,N',N'-tetrakis(4-Methoxy-phenyl)benzidine

Base Information

• Chemical Name: MeO-TPD, N,N,N',N'-tetrakis(4-Methoxy-phenyl)benzidine
• CAS No.: 244260-36-4
• Molecular Formula: C₄₀H₃₆N₂O₄
• Molecular Weight: 608.737
• Mol file: 244260-36-4.mol

Synonyms:MEO-TPD

Chemical Property of MeO-TPD, N,N,N',N'-tetrakis(4-Methoxy-phenyl)benzidine

Chemical Property:

• PSA: 43.40000
• LogP: 10.32760

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of MeO-TPD, N,N,N',N'-tetrakis(4-Methoxy-phenyl)benzidine

There total 6 articles about MeO-TPD, N,N,N',N'-tetrakis(4-Methoxy-phenyl)benzidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1-bromo-4-methoxy-benzene (104-92-7) + p,p'-diaminobiphenyl (92-87-5) → N4,N4,N4',N4'-tetrakis(4-methoxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (122738-21-0,244260-36-4)

Guidance literature:

With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate; at 110 ℃; for 12h; Inert atmosphere; Green chemistry;

DOI:10.1002/ejoc.201501616

Reference yield: 87.0%

N,N-bis(4-methoxyphenyl)aniline (20440-94-2) → N4,N4,N4',N4'-tetrakis(4-methoxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (122738-21-0,244260-36-4)

Guidance literature:

N,N-bis(4-methoxyphenyl)aniline; With copper(II) perchlorate; In acetonitrile; at 25 ℃; for 12h;

With potassium carbonate; In water; acetonitrile; at 25 ℃; for 0.5h; Further stages.;

DOI:10.1021/jo800349n

Reference yield: 80.0%

4-(4-bromophenyl)bromobenzene (92-86-4) + bis(4-methoxyphenyl)amine (101-70-2) → N4,N4,N4',N4'-tetrakis(4-methoxyphenyl)-[1,1'-biphenyl]-4,4'-diamine (122738-21-0,244260-36-4)

Guidance literature:

With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; for 4h; Glovebox; Reflux;

DOI:10.1039/c8cc00224j

upstream raw materials:

para-iodoanisole

p,p'-diaminobiphenyl

N,N-bis(4-methoxyphenyl)aniline

4-(4-bromophenyl)bromobenzene