Benzenamine, N,N-bis[4-(hexyloxy)phenyl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

Base Information

• Chemical Name: Benzenamine, N,N-bis[4-(hexyloxy)phenyl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
• CAS No.: 1221821-41-5
• Molecular Formula: C36H50BNO4
• Molecular Weight: 571.608
• Mol file: 1221821-41-5.mol

Synonyms:4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline;4,4,5,5-tetramethyl-2-{4-[N,N-bis(4-hexyloxyphenyl)amino]phenyl}-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-{4-[N,N-bis (4-hexyloxyphenyl)amino]phenyl}-1,3,2-dioxaborolane;N,N-bis[4-(hexyloxy)-phenyl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamine;4,4,5,5-tetramethyl-2-[4-[N,N-bis(4-hexyloxyphenyl)amino]phenyl]-1,3,2-dioxaborolane;4-hexyloxy-N-(4-hexyloxyphenyl)-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline;

Chemical Property of Benzenamine, N,N-bis[4-(hexyloxy)phenyl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

Chemical Property:

• Boiling Point: 665.4±50.0 °C(Predicted)
• PKA: -1.88±0.60(Predicted)
• PSA: 40.16000
• Density: 1.07±0.1 g/cm3(Predicted)
• LogP: 9.37380

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenamine, N,N-bis[4-(hexyloxy)phenyl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

There total 11 articles about Benzenamine, N,N-bis[4-(hexyloxy)phenyl]-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.9%

N,N-bis(4-hexyloxyphenyl)-4-bromophenylamine (1092363-75-1) + bis(pinacol)diborane (73183-34-3) → 4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-(4-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline (1221821-41-5)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; at 100 ℃; for 20h; Inert atmosphere;

DOI:10.1039/d1nj02610k

Reference yield: 81.0%

N,N-bis(4-hexyloxyphenyl)-N-(4-iodophenyl) amine + bis(pinacol)diborane (73183-34-3) → 4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-(4-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline (1221821-41-5)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In dimethyl sulfoxide; at 20 ℃; for 48h; Inert atmosphere;

DOI:10.1021/ol402749s

Reference yield: 55.0%

2,3-dimethyl-2,3-butane diol (76-09-5) + N,N-bis(4-hexyloxyphenyl)-4-bromophenylamine (1092363-75-1) → 4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-(4-(4,4,5,5,-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)aniline (1221821-41-5)

Guidance literature:

N,N-bis(4-hexyloxyphenyl)-4-bromophenylamine; With n-butyllithium; Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃;

2,3-dimethyl-2,3-butane diol; With magnesium sulfate; In tetrahydrofuran; at 20 ℃;

DOI:10.1016/j.tet.2014.09.039

upstream raw materials:

bis(pinacol)diborane

1-iodo-4-hexyloxybenzene

4-(hexyloxy)-N-(4-(hexyloxy)phenyl)-N-phenylaniline

1-bromo-hexane

Downstream raw materials:

C₆₇H₈₁N₃O₅S₂

2-cyano-3-{6-{4-[N,N-bis(4-hexyloxyphenyl)amino]phenyl}-4,4-dihexyl-4H-cyclopenta[2,1-b:3,4-b']dithiophene-2-yl}acrylic acid

7-{4-[N,N-bis(4-hexyloxyphenyl)amino]phenyl}-4,9-dihydro-4,4,9,9-tetrahexylsindaceno[1,2-b:5,6-b']dithiophene-2-carbaldehyde

2-cyano-3-{7-{4-[N,N-bis(4-hexyloxyphenyl)amino]phenyl}-4,9-dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b']dithiophene-2-yl}acrylic acid