Diethyl 3-[(ethoxymethanethioyl)sulfanyl]-2- oxopropyl-1-phosphonate

Base Information

• Chemical Name: Diethyl 3-[(ethoxymethanethioyl)sulfanyl]-2- oxopropyl-1-phosphonate
• CAS No.: 1006387-06-9
• Molecular Formula: C10H19O5PS2
• Molecular Weight: 314.358621
• Mol file: 1006387-06-9.mol

Synonyms:Diethyl 3-[(ethoxymethanethioyl)sulfanyl]-2-oxopropyl-1-phosphonate

Chemical Property of Diethyl 3-[(ethoxymethanethioyl)sulfanyl]-2- oxopropyl-1-phosphonate

Chemical Property:

• PSA: 129.03000
• LogP: 2.87620

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diethyl 3-[(ethoxymethanethioyl)sulfanyl]-2- oxopropyl-1-phosphonate

There total 1 articles about Diethyl 3-[(ethoxymethanethioyl)sulfanyl]-2- oxopropyl-1-phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

diethyl (3-chloro-2-oxopropyl)phosphonate (67257-29-8) + potassium ethyl xanthogenate (140-89-6) → (3-ethoxythiocarbonylsulfanyl-2-oxo-propyl)phosphonic acid diethyl ester (1006387-06-9)

Guidance literature:

In acetone; at 0 - 20 ℃;

DOI:10.1021/ol702590f

Reference yield: 90.0%

(3-ethoxythiocarbonylsulfanyl-2-oxo-propyl)phosphonic acid diethyl ester (1006387-06-9) + 2-allylcyclohexan-1-one (94-66-6) → [5-ethoxythiocarbonylsulfanyl-2-oxo-6-(2-oxo-cyclohexyl)hexyl]-phosphonic acid diethyl ester (1006387-43-4)

Guidance literature:

With dilauryl peroxide; In 1,2-dichloro-ethane; Heating;

DOI:10.1021/ol702590f

Reference yield: 81.0%

(3-ethoxythiocarbonylsulfanyl-2-oxo-propyl)phosphonic acid diethyl ester (1006387-06-9) + N-phenyl-N-(prop-2-en-1-yl)methanesulfonamide (17240-55-0) → [5-ethoxythiocarbonylsulfanyl-6-(methanesulfonyl-phenyl-amino)-2-oxo-hexyl]-phosphonic acid diethyl ester (1006387-38-7)

Guidance literature:

With dilauryl peroxide; In 1,2-dichloro-ethane; Heating;

DOI:10.1021/ol702590f

upstream raw materials:

diethyl (3-chloro-2-oxopropyl)phosphonate

potassium ethyl xanthogenate

Downstream raw materials:

(5-ethoxythiocarbonylsulfanyl-2-oxo-6-phenyl-hexyl)-phosphonic acid diethyl ester

[5-ethoxythiocarbonylsulfanyl-2-oxo-6-(2-oxo-cyclohexyl)hexyl]-phosphonic acid diethyl ester

[5-ethoxythiocarbonylsulfanyl-6-(methanesulfonyl-phenyl-amino)-2-oxo-hexyl]-phosphonic acid diethyl ester