3-Methylcyclohexanone-3-acetic acid

Base Information

Chemical Name:3-Methylcyclohexanone-3-acetic acid
CAS No.:119986-97-9
Molecular Formula:C9H14O3
Molecular Weight:170.21
Hs Code.:
Mol file:119986-97-9.mol

Synonyms:(1-Methyl-3-oxo-cyclohexyl)-essigsaeure;1-Methyl-cyclohexanon-(3)-essigsaeure-(1);[3-Oxo-1-methyl-cyclohexyl-(1)]-essigsaeure;(1-methyl-3-oxo-cyclohexyl)-acetic acid;1-methyl-3-oxo-cyclohexaneacetic acid;

Suppliers and Price of 3-Methylcyclohexanone-3-acetic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 5 raw suppliers

Chemical Property of 3-Methylcyclohexanone-3-acetic acid

Chemical Property:

Melting Point:37 °C
Boiling Point:196 °C(Press: 15 Torr)
PKA:4.55±0.10(Predicted)
PSA：54.37000
Density:1.108±0.06 g/cm3(Predicted)
LogP:1.61050

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 3-Methylcyclohexanone-3-acetic acid

There total 6 articles about 3-Methylcyclohexanone-3-acetic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.6%

: 1193-18-6
3-methylcyclohexen-2-one

: 105-53-3
diethyl malonate

: 119986-97-9
3-methylcyclohexanone-3-acetic acid

Guidance literature:: 3-methylcyclohexen-2-one; diethyl malonate; With sodium; In ethanol; at 0 ℃; for 216h;

With potassium hydroxide; for 1h; Reflux;
DOI:10.15227/orgsyn.069.0173

Reference yield:

: 68269-56-7,54735-44-3
3-methyl-3-vinylcyclohexan-1-one

: 119986-97-9
3-methylcyclohexanone-3-acetic acid

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / p-TsOH / benzene / 3 h / Heating

2: 1) BH₃*THF, 2) Jones reagent / 1) THF, 0 deg C, 1 h, 2) H₂O, -10 deg C to RT, 3 h

With jones reagent; borane-THF; toluene-4-sulfonic acid; In benzene;
DOI:10.1021/jo00068a019

Reference yield:

: 1193-18-6
3-methylcyclohexen-2-one

: 119986-97-9
3-methylcyclohexanone-3-acetic acid

Guidance literature:: Multi-step reaction with 3 steps

2: 95 percent / p-TsOH / benzene / 3 h / Heating

3: 1) BH₃*THF, 2) Jones reagent / 1) THF, 0 deg C, 1 h, 2) H₂O, -10 deg C to RT, 3 h

With jones reagent; borane-THF; toluene-4-sulfonic acid; In benzene;
DOI:10.1021/jo00068a019