9,10-dihydro-9,10-(methaniminomethano)anthracene

Base Information

• Chemical Name: 9,10-dihydro-9,10-(methaniminomethano)anthracene
• CAS No.: 24686-27-9
• Molecular Formula: C₁₆H₁₅N
• Molecular Weight: 221.302
• Mol file: 24686-27-9.mol

Synonyms:9,10-dihydro-9,10-(MethaniMinoMethano)anthracene;9,10-(Methaniminomethano)anthracene, 9,10-dihydro- (8CI,9CI)

Chemical Property of 9,10-dihydro-9,10-(methaniminomethano)anthracene

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9,10-dihydro-9,10-(methaniminomethano)anthracene

There total 4 articles about 9,10-dihydro-9,10-(methaniminomethano)anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

12-benzyloxycarbonyl-9,10-dihydro-9,10-(methaniminomethano)anthracene (793670-85-6) → 9,10-dihydro-9,10-(methaniminomethano)anthracene (24686-27-9)

Guidance literature:

With hydrogen; palladium on activated charcoal; In tetrahydrofuran; methanol; at 20 ℃; for 1.5h;

DOI:10.1081/SCC-200030972

Reference yield:

cis-9,10-dihydro-9,10-anthracenedicarboxaldehyde (81059-37-2) → 9,10-dihydro-9,10-(methaniminomethano)anthracene (24686-27-9)

Guidance literature:

With sodium cyanoborohydride; ammonium bromide; In methanol; at 60 ℃; for 2h;

DOI:10.1081/SCC-200030972

Reference yield:

12-(p-methoxyphenyl)methyl-9,10-dihydro-9,10-(methaniminomethano)anthracene (793670-84-5) → 9,10-dihydro-9,10-(methaniminomethano)anthracene (24686-27-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 93 percent / benzene / 6 h / Heating

2: 67 percent / H₂ / Pd/C / methanol; tetrahydrofuran / 1.5 h / 20 °C

With hydrogen; palladium on activated charcoal; In tetrahydrofuran; methanol; benzene;

DOI:10.1081/SCC-200030972

upstream raw materials:

cis-9,10-dihydro-9,10-anthracenedicarboxaldehyde

12-benzyloxycarbonyl-9,10-dihydro-9,10-(methaniminomethano)anthracene

12-(p-methoxyphenyl)methyl-9,10-dihydro-9,10-(methaniminomethano)anthracene