2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:912844-88-3
Molecular Formula:C18H21BO2
Molecular Weight:280.175
Hs Code.:2934999090
European Community (EC) Number:965-413-9
DSSTox Substance ID:DTXSID20591682
Wikidata:Q82485517
Mol file:912844-88-3.mol

Synonyms:912844-88-3;2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;3-Biphenylboronic acid pinacol ester;4,4,5,5-tetramethyl-2-(3-phenylphenyl)-1,3,2-dioxaborolane;C18H21BO2;biphenyl-3-boronic acid pinacol ester;MFCD18452169;2-{[1,1'-BIPHENYL]-3-YL}-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;3-Biphenylboronic acid, pinacol ester;SCHEMBL3362199;DTXSID20591682;CS-B1262;2-(BIPHENYL-3-YL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;AKOS016005606;DS-18318;SY108398;DB-104280;B6023;EN300-1706463;A860544;[1,1'-BIPHENYL]-3-YLBORONIC ACID PINACOL ESTER;Z2044738566;2-(3-Biphenylyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;2-([1,1\'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Suppliers and Price of 2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1G
$ 39.00

TCI Chemical
2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
5G
$ 99.00

Matrix Scientific
2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
250mg
$ 213.00

Matrix Scientific
2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
1g
$ 471.00

Crysdot
2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
25g
$ 465.00

Crysdot
2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
10g
$ 238.00

ChemScene
1,3,2-Dioxaborolane,2-[1,1'-biphenyl]-3-yl-4,4,5,5-tetramethyl-
1g
$ 55.00

Chem-Impex
2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane,98%(GC) 98%(GC)
5G
$ 200.48

Chem-Impex
2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane,98%(GC) 98%(GC)
1G
$ 59.36

Chemenu
2-([1,1''-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
10g
$ 82.00

Total 35 raw suppliers

Chemical Property of 2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Melting Point:82 °C
Boiling Point:412.7±24.0 °C(Predicted)
PSA：18.46000
Density:1.05±0.1 g/cm3(Predicted)
LogP:3.65280
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:280.1634601
Heavy Atom Count:21
Complexity:344

Purity/Quality:

98% ^*data from raw suppliers

2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC(=CC=C2)C3=CC=CC=C3
Uses suzuki reaction

Technology Process of 2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 21 articles about 2-([1,1'-Biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.7%

: 2113-57-7
3-bromobiphenyl

: 73183-34-3
bis(pinacol)diborane

: 912844-88-3
2-([1,1’-biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In tetrahydrofuran; at 80 ℃; for 5h; Inert atmosphere;

Reference yield: 83.0%

: 2367-22-8
3-fluorobiphenyl

: 73183-34-3
bis(pinacol)diborane

: 912844-88-3
2-([1,1’-biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; lithium hexamethyldisilazane; In toluene; at 80 ℃; for 12h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.orglett.8b02228

Reference yield: 68.0%

: ([1,1'-biphenyl]-3-yloxy)(tert-butyl)dimethylsilane

: 73183-34-3
bis(pinacol)diborane

: 912844-88-3
2-([1,1’-biphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With bis(acetylacetonate)nickel(II); lithium tert-butoxide; at 100 ℃; for 16h; Reagent/catalyst; Catalytic behavior; Sealed tube;
DOI:10.1021/acs.orglett.1c01280