m-DIOXANE, 4-(p-METHOXYPHENYL)-5-METHYL-

Base Information

Chemical Name:m-DIOXANE, 4-(p-METHOXYPHENYL)-5-METHYL-
CAS No.:5689-72-5
Molecular Formula:C12H16 O3
Molecular Weight:208.257
Hs Code.:
NSC Number:406763
DSSTox Substance ID:DTXSID50972324
Nikkaji Number:J42.117K
Mol file:5689-72-5.mol

Synonyms:4-(4-methoxyphenyl)-5-methyl-1,3-dioxane;5689-72-5;m-DIOXANE, 4-(p-METHOXYPHENYL)-5-METHYL-;NSC 406763;AI3-05533;1-(p-Methoxy phenyl)-2-methyl-1,3-propanediol methylene ether;1,3-Dioxane, 4-(4-methoxyphenyl)-5-methyl-;Formaldehyde, cyclic 1-(p-methoxyphenyl)-2-methyltrimethylene acetal;1-(p-Methoxyphenyl)-2-methyl-1,3-propanediol methylene ether;NSC406763;CC1COCOC1c2ccc(OC)cc2;DTXSID50972324;1, 4-(4-methoxyphenyl)-5-methyl-;WLN: T6O COTJ DR DO1& E1;NSC-406763;LS-62354

Suppliers and Price of m-DIOXANE, 4-(p-METHOXYPHENYL)-5-METHYL-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1-(PARA-METHOXYPHENYL)-2-METHYL-1,3-PROPANEDIOL METHYLENE ETHER 95.00%
5MG
$ 500.51

Total 5 raw suppliers

Chemical Property of m-DIOXANE, 4-(p-METHOXYPHENYL)-5-METHYL-

Chemical Property:

Vapor Pressure:0.00126mmHg at 25°C
Boiling Point:308.2°Cat760mmHg
Flash Point:102.8°C
PSA：27.69000
Density:1.058g/cm³
LogP:2.37670
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:208.109944368
Heavy Atom Count:15
Complexity:187

Purity/Quality:

99% ^*data from raw suppliers

1-(PARA-METHOXYPHENYL)-2-METHYL-1,3-PROPANEDIOL METHYLENE ETHER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1COCOC1C2=CC=C(C=C2)OC

Technology Process of m-DIOXANE, 4-(p-METHOXYPHENYL)-5-METHYL-

There total 4 articles about m-DIOXANE, 4-(p-METHOXYPHENYL)-5-METHYL- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 104-46-1,25086-72-0,63589-56-0
anethole

: 5689-72-5
4-p-methoxyphenyl-5-methyl-1,3-dioxane

Guidance literature:: Lewatit SP 120 (acid form); In 1,4-dioxane; at 60 ℃; for 0.5h;
DOI:10.1055/s-1980-29243

Reference yield: 97.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 4180-23-8,25086-72-0,63589-56-0
E-1-(4'-methoxyphenyl)prop-1-ene

: 5689-72-5
4-p-methoxyphenyl-5-methyl-1,3-dioxane

Guidance literature:: resine C₃₅O; hydrogen cation; In benzene; at 60 ℃; for 12h;
DOI:10.1016/0040-4039(81)80133-5

Reference yield:

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 4180-23-8,25086-72-0,63589-56-0
E-1-(4'-methoxyphenyl)prop-1-ene

: 2036-03-5,5689-72-5,84363-00-8
trans-4-Methoxyphenyl-5-methyl-1,3-dioxan

: trans-5-methyl-4-phenyl-1,3-dioxane

Guidance literature:: With 1,1,1-trifluoro-N-((11bS)-4-(((11bS)-4-oxido-2,6-bis(4-(trifluoromethyl)phenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)imino)-2,6-bis(4-(trifluoromethyl)phenyl)-4λ5-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide; In cyclohexane; at 25 ℃; for 96h; Overall yield = 48 percent; Optical yield = 29 percent ee; diastereoselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/jacs.1c10245