1-Butyl-3-methylimidazolium Tetrachloroferrate

Base Information

• Chemical Name: 1-Butyl-3-methylimidazolium Tetrachloroferrate
• CAS No.: 359845-21-9
• Molecular Formula: C8H15N2.Cl4Fe
• Molecular Weight: 336.88
• Hs Code.: 2933290090
• European Community (EC) Number: 678-175-3
• Wikipedia: 1-Butyl-3-methylimidazolium_tetrachloroferrate
• Mol file: 359845-21-9.mol

Synonyms:359845-21-9;1-Butyl-3-methylimidazolium Tetrachloroferrate;1-Butyl-3-methyl-1H-imidazol-3-ium tetrachloroferrate(III);1-butyl-3-methylimidazol-3-ium;tetrachloroiron(1-);SCHEMBL914812;DTXCID5029138;DTXSID0049282;Tox21_202620;MFCD08276298;AKOS027320760;NCGC00260168-01;B2672;CAS-359845-21-9;D88948;A874473;1-Butyl-3-methylimidazolium tetrachloroferrate(III);1-Butyl-3-methylimidazolium tetrachloroferrate (III);1-Butyl-3-methyl-1H-imidazol-3-iumtetrachloroferrate(III)

Chemical Property of 1-Butyl-3-methylimidazolium Tetrachloroferrate

Chemical Property:

• Melting Point: -11℃
• PSA: 8.81000
• Density: 1.38 g/cm3
• LogP: 3.86820
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 336.930920
• Heavy Atom Count: 15
• Complexity: 112

Purity/Quality:

99% ^*data from raw suppliers

1-Butyl-3-methylimidazolium Tetrachloroferrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCN1C=C[N+](=C1)C.Cl[Fe-](Cl)(Cl)Cl
• General Description: 1-Butyl-3-methylimidazolium tetrachloroferrate ([bmim]FeCl₄) is a magnetic ionic liquid that exhibits strong paramagnetic behavior with a high magnetic susceptibility of 40.6 × 10^-6 emu g^-1, as confirmed by SQUID measurements. It is synthesized by combining 1-butyl-3-methylimidazolium chloride ([bmim]Cl) and FeCl₃, forming a liquid with high-spin FeCl₄^- anions and [bmim]⁺ cations. This ionic liquid demonstrates significant responsiveness to external magnetic fields and has potential applications in areas such as liquid magnetism and materials synthesis, including the ionothermal production of mesoporous graphite nanoflakes for water purification.

Technology Process of 1-Butyl-3-methylimidazolium Tetrachloroferrate

There total 5 articles about 1-Butyl-3-methylimidazolium Tetrachloroferrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

iron(III) chloride hexahydrate + 1-butyl-3-methylimidazolium chloride (79917-90-1) → 1-butyl-3-methylimidazolium tetrachloridoferrate(III) (359845-21-9)

Guidance literature:

for 0.0833333h;

DOI:10.1007/s11426-012-4657-z

Reference yield:

→ 1-butyl-3-methylimidazolium tetrachloridoferrate(III) (359845-21-9) + 1-butyl-3-methylimidazolium chloride (79917-90-1)

Guidance literature:

Reference yield:

iron(III) chloride + 1-butyl-3-methylimidazolium chloride (79917-90-1) → 1-butyl-3-methylimidazolium tetrachloridoferrate(III) (359845-21-9)

Guidance literature:

at 20 ℃;

DOI:10.1039/c3ra43585g

upstream raw materials:

iron(III) chloride hexahydrate

1-butyl-3-methylimidazolium chloride

iron(III) chloride

Downstream raw materials:

succinic acid ethyl ester methyl ester

succinic acid diethyl ester

Dimethyl succinate