Benzeneacetic acid, 2,3,4,5,6-pentachloro-α-hydroxy-α-(pentachlorophenyl)-, 1-methylethyl ester (9CI)

Base Information

• Chemical Name: Benzeneacetic acid, 2,3,4,5,6-pentachloro-α-hydroxy-α-(pentachlorophenyl)-, 1-methylethyl ester (9CI)
• CAS No.: 112312-91-1
• Molecular Formula: C₁₇H₈Cl₁₀O₃
• Molecular Weight: 614.779
• Mol file: 112312-91-1.mol

Synonyms:

Chemical Property of Benzeneacetic acid, 2,3,4,5,6-pentachloro-α-hydroxy-α-(pentachlorophenyl)-, 1-methylethyl ester (9CI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzeneacetic acid, 2,3,4,5,6-pentachloro-α-hydroxy-α-(pentachlorophenyl)-, 1-methylethyl ester (9CI)

There total 3 articles about Benzeneacetic acid, 2,3,4,5,6-pentachloro-α-hydroxy-α-(pentachlorophenyl)-, 1-methylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexachlorobenzene (118-74-1,67471-27-6) → isopropyl decachlorobenzilate (112312-91-1)

Guidance literature:

Multi-step reaction with 2 steps

1: Mg / tetrahydrofuran

With magnesium; In tetrahydrofuran;

DOI:10.1016/S0040-4039(01)81019-4

Reference yield:

diisopropyl oxalate (615-81-6) + hexachlorobenzene (118-74-1,67471-27-6) → isopropyl decachlorobenzilate (112312-91-1)

Guidance literature:

With magnesium; ethylene dibromide; Yield given. Multistep reaction; 1) THF, 2) r.t., 1 h;

DOI:10.1055/s-1993-25911

Reference yield:

diisopropyl oxalate (615-81-6) + pentachlorophenylmagnesium chloride (31279-13-7) → isopropyl decachlorobenzilate (112312-91-1)

Guidance literature:

DOI:10.1016/S0040-4039(01)81019-4

upstream raw materials:

diisopropyl oxalate

hexachlorobenzene

pentachlorophenylmagnesium chloride

Downstream raw materials:

C₁₈H₈Cl₁₀NO₂^(1-)

C₁₇H₇Cl₁₀O₂^(1-)

C₁₄Cl₁₀N^(1-)

Bis-pentachlorophenyl-acetyl chloride

Refernces

• 1、 Hegarty,O'Neill. "Synthesis of sterically congested acetic acid derivatives: The reaction of hindered α-oxo esters with pentasubstituted aryl Grignard reagents". . p. 606 - 610. Retrieved 2007/10/02.