meso-tetra-(3,5-di-t-butylphenyl)porphine

Base Information

• Chemical Name: meso-tetra-(3,5-di-t-butylphenyl)porphine
• CAS No.: 89372-90-7
• Molecular Formula: C76H94N4
• Molecular Weight: 1063.61
• Mol file: 89372-90-7.mol

Synonyms:2,7,12,17-Tetrakis(3,5-di-tert-butylphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.13,6; 5,10,15,20-Tetrakis(3,5-di-tert-butylphenyl)porphyrin

Chemical Property of meso-tetra-(3,5-di-t-butylphenyl)porphine

Chemical Property:

• PSA: 56.30000
• Density: 1.038g/cm³
• LogP: 17.24620

Purity/Quality:

98% purity ^*data from raw suppliers

meso-Tetra-(3,5-di-t-butylphenyl)porphine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: meso-Tetra-(3,5-di-t-butylphenyl)porphine is a synthetic porphyrin.

Technology Process of meso-tetra-(3,5-di-t-butylphenyl)porphine

There total 43 articles about meso-tetra-(3,5-di-t-butylphenyl)porphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

{meso-tetrakis[3,5-bis(tert-butyl)phenyl]porphyrinato}zinc(II) → 5,10,15,20-tetrakis-(3,5-di-tert-butylphenyl)porphyrin (89372-90-7)

Guidance literature:

With S-(trifluoromethyl)-3,7-dinitrobenzothiophene-CF₃SO₃^(1-); In tetrahydrofuran;

DOI:10.1002/(sici)1099-0690(199910)1999:10<2471::aid-ejoc2471>3.0.co;2-y

Reference yield: 43.0%

pyrrole (109-97-7,30604-81-0) + 3,5-Di-tert-butylbenzaldehyde (17610-00-3) → 5,10,15,20-tetrakis-(3,5-di-tert-butylphenyl)porphyrin (89372-90-7)

Guidance literature:

pyrrole; 3,5-Di-tert-butylbenzaldehyde; With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 3h; Darkness; Inert atmosphere;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; for 1h;

With triethylamine; In dichloromethane;

DOI:10.1002/chem.201300219

Reference yield: 27.0%

pyrrole (109-97-7,30604-81-0) + 3,5-Di-tert-butylbenzaldehyde (17610-00-3) + 2,6-dichloro-pyrimidine carbaldehyde (5305-40-8) → 5,10,15,20-tetrakis-(3,5-di-tert-butylphenyl)porphyrin (89372-90-7) + (1Z,4Z,9Z,15Z)-5,20-Bis-(3,5-di-tert-butyl-phenyl)-10,15-bis-(4,6-dichloro-pyrimidin-5-yl)-porphyrin + 5,15-bis[3,5-bis(tert-butyl)phenyl]-10,20-bis[4,6-dichloropyrimidin-5-yl]porphyrin + (5Z,10Z,14Z,19Z)-5,10,15-Tris-(3,5-di-tert-butyl-phenyl)-20-(4,6-dichloro-pyrimidin-5-yl)-porphyrin

Guidance literature:

pyrrole; 3,5-Di-tert-butylbenzaldehyde; 2,6-dichloro-pyrimidine carbaldehyde; With boron trifluoride diethyl etherate; In dichloromethane;

With chloranil;

DOI:10.1016/S0040-4039(99)01571-3

upstream raw materials:

pyrrole

3,5-Di-tert-butylbenzaldehyde

4′-formyl-2,2′:6′2″-terpyridine

Propionic acid 4-[9-(4-formyl-phenyl)-[1,10]phenanthrolin-2-yl]-benzyl ester

Downstream raw materials:

{5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrinato}silver(II)

C₇₆H₉₂N₄Zn