[5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Base Information

• Chemical Name: [5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)
• CAS No.: 146164-93-4
• Molecular Formula: C₇₆H₉₂CuN₄
• Molecular Weight: 1125.14
• Mol file: 146164-93-4.mol

Synonyms:[5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Chemical Property of [5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

There total 4 articles about [5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

5,10,15,20-tetrakis[(3,5-di-tert-butylphenyl)]porphyrin + copper(II) acetate monohydrate (6046-93-1) → [5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (146164-93-4)

Guidance literature:

In methanol; dichloromethane; refluxing a mixt. of porphyrine and copper salt in CH2Cl2 and CH3OH for 1.5 h, cooling; evapn., passing through a plug of silica (CH2Cl2), evapn.;

DOI:10.1039/b007389j

Reference yield: 93.0%

5,10,15,20-tetrakis-(3,5-di-tert-butylphenyl)porphyrin (89372-90-7) → [5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (146164-93-4)

Guidance literature:

With copper acetate supported on propionic acid/silica gel; at 111 ℃; for 0.25h; Microwave irradiation;

DOI:10.1002/jhet.78

Reference yield:

[Cu(tetrakis(3,5-di-tert-butylphenyl)porphine(-2H))]*2C6H6 → [5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) (146164-93-4)

Guidance literature:

In neat (no solvent); byproducts: C6H6; heated in air to 250°C at a heating rate of 2.5 K/min;

upstream raw materials:

copper(II) acetate monohydrate

5,10,15,20-tetrakis-(3,5-di-tert-butylphenyl)porphyrin

copper diacetate

Downstream raw materials:

2-formyl-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinatocopper(II)

(2,3,7,8-tetraoxo-5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)isobacteriochlorinato)zinc(II)

[2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)