meso-Tetra (4-chlorophenyl) porphine

Base Information

• Chemical Name: meso-Tetra (4-chlorophenyl) porphine
• CAS No.: 22112-77-2
• Molecular Formula: C44H26Cl4N4
• Molecular Weight: 752.529
• Mol file: 22112-77-2.mol

Synonyms:2,7,12,17-tetra(4-chlorophenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1~3,6~.1~8,11~.1~13,16~]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene; 21H,23H-porphine, 5,10,15,20-tetrakis(4-chlorophenyl)-; 5,10,15,20-Tetrakis(4-chlorophenyl)porphyrin; meso-Tetra (4-chlorophenyl) porphine

Chemical Property of meso-Tetra (4-chlorophenyl) porphine

Chemical Property:

• Melting Point: >27 °C
• PSA: 56.30000
• Density: 1.398g/cm³
• LogP: 9.47980
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

99% ^*data from raw suppliers

5,10,15,20-Tetrakis(4-chlorophenyl)porphyrin 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of meso-Tetra (4-chlorophenyl) porphine

There total 20 articles about meso-Tetra (4-chlorophenyl) porphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

pyrrole (109-97-7,30604-81-0) + 4-chlorobenzaldehyde (104-88-1) → 5,10,15,20-tetra-(4-chlorophenyl)porphyrin (22112-77-2)

Guidance literature:

With vanadium(V) oxychloride; In dichloromethane; for 1h; Ambient temperature; other reagents: TiCl₄, VO(OEt)Cl₂, VO(OiPr)Cl₂, Mn(OAc)3;

Reference yield: 50.0%

2-bromo-5,10,15,20-tetrakis-(4-chloro-phenyl)-porphyrine → C44H24Cl4N4 + 5,10,15,20-tetra-(4-chlorophenyl)porphyrin (22112-77-2)

Guidance literature:

With potassium carbonate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In N,N-dimethyl-formamide; at 130 ℃; for 0.5h;

DOI:10.1021/jo0609677

Reference yield: 21.0%

4-chlorobenzaldehyde (104-88-1) + 2,2'-((4-chlorophenyl)methylene)bis(1H-pyrrole) (137018-26-9) → 5,10,15,20-tetra-(4-chlorophenyl)porphyrin (22112-77-2)

Guidance literature:

4-chlorobenzaldehyde; 2,2'-((4-chlorophenyl)methylene)bis(1H-pyrrole); With Indion-130 resin; In dichloromethane; at 25 ℃; for 17h;

With chloranil; In dichloromethane; for 3h; Heating;

DOI:10.1016/S0040-4020(03)00245-X

upstream raw materials:

pyrrole

4-chlorobenzaldehyde

tetrakis(4-aminophenyl)porphyrin

(4-Chloro-phenyl)-(1H-pyrrol-2-yl)-methanol

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