5,10,15,20-TETRAKIS(4-AMINOPHENYL)-21H,23H-PORPHINE

Base Information

• Chemical Name: 5,10,15,20-TETRAKIS(4-AMINOPHENYL)-21H,23H-PORPHINE
• CAS No.: 22112-84-1
• Molecular Formula: C44H34 N8
• Molecular Weight: 674.808
• Hs Code.: 29339900
• Mol file: 22112-84-1.mol

Synonyms:Porphine,5,10,15,20-tetrakis(p-aminophenyl)- (8CI); 5,10,15,20-Tetra(4-aminophenyl)porphyrin;5,10,15,20-Tetrakis(4-aminophenyl)-21H,23H-porphine;5,10,15,20-Tetrakis(4-aminophenyl)porphine;5,10,15,20-Tetrakis(4-aminophenyl)porphyrin;5,10,15,20-Tetrakis(p-aminophenyl)porphyrin; Tetra(p-aminophenyl)porphyrin;Tetrakis(p-aminophenyl)porphyrin; meso-Tetra(4-aminophenyl)porphyrin;meso-Tetra(p-aminophenyl)porphine; meso-Tetrakis(4-aminophenyl)porphyrin;meso-Tetrakis(p-aminophenyl)porphine; a,b,g,d-Tetrakis(4-aminophenyl)porphine

Chemical Property of 5,10,15,20-TETRAKIS(4-AMINOPHENYL)-21H,23H-PORPHINE

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 160.38000
• Density: 1.35g/cm³
• LogP: 7.51980
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

98%,99%, ^*data from raw suppliers

5,10,15,20-Tetrakis(4-aminophenyl)porphyrin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 5,10,15,20-Tetrakis(4-aminophenyl)porphyrin (CAS# 22112-84-1) is a porphyrin derivative used in the preparation of metal complexes, such as those of Fe(III) for the use of catalyzing the electrochemical oxygen reduction reaction.

Technology Process of 5,10,15,20-TETRAKIS(4-AMINOPHENYL)-21H,23H-PORPHINE

There total 13 articles about 5,10,15,20-TETRAKIS(4-AMINOPHENYL)-21H,23H-PORPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

5,10,15,20-tetrakis(4-nitrophenyl)porphyrin (22843-73-8) → tetrakis(4-aminophenyl)porphyrin (22112-84-1)

Guidance literature:

5,10,15,20-tetrakis(4-nitrophenyl)porphyrin; With hydrogenchloride; In water; for 0.5h; Inert atmosphere;

With tin(II) chloride dihdyrate; In water; at 80 ℃; for 0.5h; Inert atmosphere;

DOI:10.1088/0957-4484/21/6/065102

Reference yield: 90.0%

zinc(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine (67595-98-6) → tetrakis(4-aminophenyl)porphyrin (22112-84-1)

Guidance literature:

With pyridine; pyridine hydrochloride; for 2h; Inert atmosphere;

Reference yield: 74.0%

pyrrole (109-97-7,30604-81-0) + 4-aminobenzaldehyde (556-18-3,28107-09-7) → tetrakis(4-aminophenyl)porphyrin (22112-84-1)

Guidance literature:

With toluene-4-sulfonic acid; In N,N-dimethyl-formamide;

DOI:10.1142/S1088424619500093

upstream raw materials:

5,10,15,20-tetrakis(4-nitrophenyl)porphyrin

pyrrole

4-nitrobenzaldehdye

zinc(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine

Downstream raw materials:

N,N-dimethyl-4-[(5,10′,14′′,19′′′ )-10,15,20-tris(4-dimethylaminophenyl)-21,23-dihydroporphyrin-5-yl]aniline

meso-tetrakis<(p-trimethylammonio)phenyl>porphyrin tetraiodide

5,10,15,20-tetrakis(4-aminophenyl)porphinatocobalt

meso-tetrakis(4-acetamidophenyl)porphyrin

Refernces

• 1、 Xue, Zhi,Lee, Priscilla P.S.,Wang, Yanming,Kwong, Daniel W.J.,Li, Jing,Xin, John H.,Wong, Wai-Kwok,Cheuk, Kevin K.L.. "Further insight into aryl nitration of tetraphenylporphyrin". . p. 6030 - 6035. Retrieved 2011.
• 2、 Lian, Wenhui,Sun, Yuanyuan,Wang, Binbin,Shan, Ning,Shi, Tongshun. "Synthesis and properties of 5,10,15,20-tetrakis[4-(3,5-dioctyloxybenzamido) phenyl]porphyrin and its metal complexes". . p. 335 - 348. Retrieved 2012.
• 3、 Semeikin, A. S.,Koifman, O. I.,Berezin, B. D.. "SYNTHESIS OF TETRAPHENYLPORPHINS WITH ACTIVE GROUPS IN THE PHENYL RINGS. 1. PREPARATION OF TETRAKIS(4-AMINOPHENYL)PORPHIN". . p. 1046 - 1047. Retrieved 1982.
• 4、 Liu, Guoli,Lv, Hongying,Zhao, Jing,Zhang, Shen,Sun, Shuqing. "Novel graphene capsule-aminoporphyrin nanohybrids: Preparation and application in photodynamic therapy of cancer". . p. 56062 - 56072. Retrieved 2017.
• 5、 Pei, Jinghe,Gao, Bo,Li, Yanhui,Duan, Qian. "Synthesis of novel porphyrin derivatives and their self-assemblies to enhance photocatalytic performance". . p. 3454 - 3462. Retrieved 2021.
• 6、 Xu, Xiao-Ling,Lin, Fu-Wen,Xu, Wei,Wu, Jian,Xu, Zhi-Kang. "Highly sensitive INHIBIT and XOR logic gates based on ICT and ACQ emission switching of a porphyrin derivative". . p. 984 - 987. Retrieved 2015.
• 7、 Zhang, Qingxin,Wang, Yabo,Wang, Yanzhi,Yang, Shujiao,Wu, Xuan,Lv, Bin,Wang, Ni,Gao, Yimei,Xu, Xiaoran,Lei, Haitao,Cao, Rui. "Electropolymerization of cobalt porphyrins and corroles for the oxygen evolution reaction". . p. 3807 - 3810. Retrieved 2021.
• 8、 Zhai, Le,Yang, Ke-Wu. "Porphyrin-vancomycin: A highly promising conjugate for the identification and photodynamic inactivation of antibiotic resistant Gram-positive pathogens". . p. 228 - 238. Retrieved 2015.
• 9、 Yuasa, Makoto,Oyaizu, Kenichi,Yamaguchi, Aritomo,Kuwakado, Michi. "Micellar cobaltporphyrin nanorods in alcohols". . p. 11128 - 11129. Retrieved 2004.
• 10、 Chaudhri, Nivedita,Sawhney, Nipun,Madhusudhan, Bijjam,Raghav, Anubhav,Sankar, Muniappan,Satapathi, Soumitra. "Effect of functional groups on sensitization of dye-sensitized solar cells (DSSCs) using free base porphyrins". . p. 222 - 230. Retrieved 2017.