MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER

Base Information

• Chemical Name: MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER
• CAS No.: 22112-83-0
• Molecular Formula: C52H38N4O8
• Molecular Weight: 846.896
• Mol file: 22112-83-0.mol

Synonyms:T(-COOCH3)PPH2; S-(2-hydroxypropanoate; Lactoyl-coenzyme A; 5,10,15,20-meso-tetrakis(4-(methylcarboxy)phenyl)-21H,23H-porphine; tetramethyl 4,4',4'',4'''-porphyrin-5,10,15,20-tetrabenzoate; Coenzyme A,lactoyl; 4-COOMe-H2TPP; 2-hydroxypropionyl CoA; Lactoyl-CoA; Lactyl-coa; 2-hydroxypropanoyl CoA; 查看更多英文别名 收起

Chemical Property of MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER

Chemical Property:

• Melting Point: 250 °C
• PSA: 161.50000
• Density: 1.319±0.06 g/cm3(Predicted)
• LogP: 6.01260

Purity/Quality:

98%,99%, ^*data from raw suppliers

meso-Tetra(4-carboxyphenyl)porphinetetramethylester >95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER

There total 30 articles about MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

pyrrole (109-97-7,30604-81-0) + methyl 4-formylbenzoate (1571-08-0) → 5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin (22112-83-0)

Guidance literature:

In propionic acid; for 20h; Reflux;

DOI:10.1002/chem.202005427

Reference yield: 40.0%

pyrrole (109-97-7,30604-81-0) + propionic acid (802294-64-0,79-09-4) + methyl 4-formylbenzoate (1571-08-0) → 5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin (22112-83-0)

Guidance literature:

propionic acid; methyl 4-formylbenzoate; at 80 ℃;

pyrrole; at 140 ℃; for 1h;

DOI:10.1016/j.tet.2021.132213

Reference yield: 22.0%

pyrrole (109-97-7,30604-81-0) + methyl 4-acetylbenzoate (3609-53-8) → 5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin (22112-83-0)

Guidance literature:

In propionic acid; for 10h; Reflux; Darkness;

DOI:10.1021/jacs.1c10291

upstream raw materials:

pyrrole

methyl 4-formylbenzoate

methanol

tetrakis(4-carboxyphenyl)porphyrin

Downstream raw materials:

tetra methyl 4,4′,4″,4′″-(copperporphyrin-5,10,15,20-tetrayl)tetrabenzoate

C₅₂H₃₆N₄O₈Rh⁽¹⁺⁾*Cl^(1-)

5,10,15,20-tetrakis(p-chloromethylphenyl)porphyrin

Refernces

• 1、 Bodedla, Govardhana Babu,Wong, Wai-Yeung,Zhu, Xunjin. "Coupling of a new porphyrin photosensitizer and cobaloxime cocatalyst for highly efficient photocatalytic H2evolution". . p. 20645 - 20652. Retrieved 2021.
• 2、 Manivannan, Ramalingam,Ryu, Jiwon,Son, Young-A. "Ultrasonic assisted fabrication of dual function surface on PET and preparation of single component ink to attain efficient self-cleaning function via digital printing". . . Retrieved 2021.
• 3、 Zhang, Ding-Wa,Chen, Wen-Tong. "Two novel tcpp porphyrinic compounds: In situ syntheses, characterization and reaction mechanism". . p. 3381 - 3385. Retrieved 2017.
• 4、 Feng, Dawei,Gu, Zhi-Yuan,Li, Jian-Rong,Jiang, Hai-Long,Wei, Zhangwen,Zhou, Hong-Cai. "Zirconium-metalloporphyrin PCN-222: Mesoporous metal-organic frameworks with ultrahigh stability as biomimetic catalysts". . p. 10307 - 10310,4. Retrieved 2012.
• 5、 Rudine, Alexander B.,Delfatti, Brian D.,Wamser, Carl C.. "Spectroscopy of protonated tetraphenylporphyrins with amino/carbomethoxy substituents: Hyperporphyrin effects and evidence for a monoprotonated porphyrin". . p. 6040 - 6049. Retrieved 2013.
• 6、 Hamid, Sheida,Mouradzadegun, Arash. "Design and Synthesis of Supramolecular Polymer Network Equipped with Pd-porphyrin: An Efficient and Recoverable Heterogeneous Catalyst for C–C Coupling Reactions". . p. 658 - 669. Retrieved 2021.
• 7、 Feng, Dawei,Gu, Zhi-Yuan,Chen, Ying-Pin,Park, Jihye,Wei, Zhangwen,Sun, Yujia,Bosch, Mathieu,Yuan, Shuai,Zhou, Hong-Cai. "A highly stable porphyrinic zirconium metal-organic framework with shp-a topology". . p. 17714 - 17717. Retrieved 2014.
• 8、 Alexandrov, Eugeny V.,Fang, Zhi-Bin,Huang, Qian-Qian,Li, Yu-Lin,Liu, Tian-Fu,Proserpio, Davide M.,Qin, Wei-Kang,Si, Duan-Hui,Yin, Qi,Zhang, An-An,Zhang, Yuan. "Metallization-Prompted Robust Porphyrin-Based Hydrogen-Bonded Organic Frameworks for Photocatalytic CO2 Reduction". supporting information. . Retrieved 2021/12/24.
• 9、 Lorenz, Patrick,Luchs, Tobias,Hirsch, Andreas. "Molecular Solar Thermal Batteries through Combination of Magnetic Nanoparticle Catalysts and Tailored Norbornadiene Photoswitches". supporting information. p. 4993 - 5002. Retrieved 2021/02/26.