5,10,15,20-Tetrakis(4-fluorophenyl)porphyrin

Base Information

• Chemical Name: 5,10,15,20-Tetrakis(4-fluorophenyl)porphyrin
• CAS No.: 37095-43-5
• Molecular Formula: C44H26F4N4
• Molecular Weight: 686.711
• DSSTox Substance ID: DTXSID20457476
• Mol file: 37095-43-5.mol

Synonyms:DTXSID20457476;5,10,15,20-Tetrakis(4-fluorophenyl)porphyrin;5,10,15,20-tetrakis(4-fluorophenyl)-21,22-dihydroporphyrin

Chemical Property of 5,10,15,20-Tetrakis(4-fluorophenyl)porphyrin

Chemical Property:

• Melting Point: >300 °C
• PSA: 56.30000
• Density: 1.354g/cm³
• LogP: 7.42260
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• XLogP3: 10.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 686.20935949
• Heavy Atom Count: 52
• Complexity: 1080

Purity/Quality:

97% ^*data from raw suppliers

5,10,15,20-Tetrakis(4-fluorophenyl)-21H,23H-porphine 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C2=C3C=CC(=C(C4=CC=C(N4)C(=C5C=CC(=N5)C(=C6C=CC2=N6)C7=CC=C(C=C7)F)C8=CC=C(C=C8)F)C9=CC=C(C=C9)F)N3)F

Technology Process of 5,10,15,20-Tetrakis(4-fluorophenyl)porphyrin

There total 6 articles about 5,10,15,20-Tetrakis(4-fluorophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.2%

pyrrole (109-97-7,30604-81-0) + 4-fluorobenzaldehyde (459-57-4) → 5,10,15,20-tetrakis(p-fluorophenyl)porphyrin (37095-43-5)

Guidance literature:

pyrrole; 4-fluorobenzaldehyde; In cyclohexane; propionic acid; at 158.2 ℃; for 0.15h; under 3800.26 Torr; Large scale; Green chemistry;

With air; In cyclohexane; propionic acid; for 0.5h; Large scale; Green chemistry;

Reference yield: 19.0%

4-fluorobenzaldehyde (459-57-4) + 2,2'-((4-fluorophenyl)methylene)bis(1H-pyrrole) (221247-13-8) → 5,10,15,20-tetrakis(p-fluorophenyl)porphyrin (37095-43-5)

Guidance literature:

4-fluorobenzaldehyde; 2,2'-((4-fluorophenyl)methylene)bis(1H-pyrrole); With Indion-130 resin; In dichloromethane; at 25 ℃; for 17h;

With chloranil; In dichloromethane; for 3h; Heating;

DOI:10.1016/S0040-4020(03)00245-X

Reference yield:

C44H32F4N4 → 5,10,15,20-tetrakis(p-fluorophenyl)porphyrin (37095-43-5)

Guidance literature:

for 2.5h; UV-irradiation;

DOI:10.1246/cl.2008.112

upstream raw materials:

pyrrole

4-fluorobenzaldehyde

tetrakis(4-aminophenyl)porphyrin

2,2'-((4-fluorophenyl)methylene)bis(1H-pyrrole)

Downstream raw materials:

C₄₄H₂₄F₄N₄Rh⁽¹⁺⁾*Cl^(1-)

Ag(p-FTPP)

meso-tetra(4-chlorophenyl)porphyrinatoaluminum chloride

5,10,15,20-tetra(4-fluorophenyl) porphyrinato manganese chloride