furan-2-acrylic acid azide

Base Information

• Chemical Name: furan-2-acrylic acid azide
• CAS No.: 119924-26-4
• Molecular Formula: C₇H₅N₃O₂
• Molecular Weight: 163.136
• Hs Code.: 2932190090
• Mol file: 119924-26-4.mol

Synonyms:HcODADI`Di[dfU^U]ZUiiAAP;(E)-3-(furan-2-yl)acryloyl azide;

Chemical Property of furan-2-acrylic acid azide

Chemical Property:

• Melting Point: 70-72 °C(Solv: ethyl ether (60-29-7); hexane (110-54-3))
• PSA: 79.96000
• LogP: 1.58246

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of furan-2-acrylic acid azide

There total 6 articles about furan-2-acrylic acid azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

3-(fur-2-yl)crotonic acid (539-47-9,15690-24-1) → (E)-3-(2-furanyl)-2-propenoyl azide (119924-26-4)

Guidance literature:

With diphenyl phosphoryl azide; triethylamine; In tetrahydrofuran; at 25 ℃; for 4h; Cooling with ice;

Reference yield: 75.0%

(E)-1-(1H-1,2,3-benzotriazol-1-yl)-3-(2-furyl)-2-propen-1-one (519054-08-1) → (E)-3-(2-furanyl)-2-propenoyl azide (119924-26-4)

Guidance literature:

With sodium azide; In water; acetonitrile; at 20 ℃; for 16h;

DOI:10.1021/jo070162e

Reference yield:

(E)-3-(2-furyl)acryloyl chloride (20689-54-7,63485-67-6,79148-89-3) → (E)-3-(2-furanyl)-2-propenoyl azide (119924-26-4)

Guidance literature:

With sodium azide; In water; at 0 ℃; for 1h;

DOI:10.1021/jm00142a024

upstream raw materials:

(E)-3-(2-furyl)acryloyl chloride

(E)-1-(1H-1,2,3-benzotriazol-1-yl)-3-(2-furyl)-2-propen-1-one

3-(fur-2-yl)crotonic acid

chloroformic acid ethyl ester

Downstream raw materials:

5H-furo[3,2-c]pyridin-4-one

7-bromofuro[3,2-c]pyridine-4(5H)-one

furo[3,2-c]pyridine-4-ol

4-chlorofuro[3,2-c]pyridine