11,12-Dihydro-11-phenylindolo[2,3-a]carbazole

Base Information

• Chemical Name: 11,12-Dihydro-11-phenylindolo[2,3-a]carbazole
• CAS No.: 1024598-06-8
• Molecular Formula: C24H16N2
• Molecular Weight: 332.404
• Mol file: 1024598-06-8.mol

Synonyms:11,12-dihydro-11-phenyl-Indolo[2,3-a]carbazole; Indolo[2,3-a]carbazole, 11,12-dihydro-11-phenyl-;

Chemical Property of 11,12-Dihydro-11-phenylindolo[2,3-a]carbazole

Chemical Property:

• Boiling Point: 598.8±32.0 °C(Predicted)
• PKA: 16.78±0.30(Predicted)
• PSA: 20.72000
• Density: 1.26
• LogP: 6.41820
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98% ^*data from raw suppliers

11-Phenyl-11,12-dihydroindolo[2,3-a]carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 11,12-Dihydro-11-phenylindolo[2,3-a]carbazole

There total 15 articles about 11,12-Dihydro-11-phenylindolo[2,3-a]carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

bromobenzene (108-86-1,52753-63-6) + 11,12-dihydroindolo[2,3-a]carbazole (60511-85-5) → 11-phenyl-11,12-dihydroindolo[2,3-a]carbazole (1024598-06-8)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; sodium t-butanolate; In o-xylene; at 160 ℃; for 48h;

Reference yield: 78.4%

9-phenyl-9H-carbazol-1-amine (855180-11-9) + (2-bromophenyl)boronic acid (244205-40-1) → 11-phenyl-11,12-dihydroindolo[2,3-a]carbazole (1024598-06-8)

Guidance literature:

9-phenyl-9H-carbazol-1-amine; With hydrogen bromide; dihydrogen peroxide; In water; acetonitrile; at -20 ℃;

(2-bromophenyl)boronic acid; With palladium diacetate; caesium carbonate; (R_P,R_P)-1,2-bis[(o-anisyl)(phenyl)phosphino]ethane; In 1-methyl-pyrrolidin-2-one; at 20 ℃; Inert atmosphere; Reflux;

Reference yield: 77.0%

→ 11-phenyl-11,12-dihydroindolo[2,3-a]carbazole (1024598-06-8)

Guidance literature:

With bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In toluene; at 95 ℃; for 4h;

upstream raw materials:

iodobenzene

11,12-dihydroindolo[2,3-a]carbazole

phenylhydrazine hydrochloride

cyclohexane-1,2-dione

Downstream raw materials:

C₇₅H₄₅N₉

C₅₈H₃₆N₆

11-(4,6-diphenyl-1,3,5-triazin-2-yl)-12-phenyl-11,12-dihydroindolo[2,3-a]carbazole

C₄₁H₂₇N₃

Refernces

• 1、 -. "Novel hetero-cyclic compound and organic light emitting device comprising the same". Paragraph 0183-0186. . Retrieved 2021/06/01.
• 2、 -. "Organic compound, electronic component using same, and electronic device". Paragraph 0180-0182. . Retrieved 2021/12/07.