2-Cyclopropoxyphenylboronic acid

Base Information

Chemical Name:2-Cyclopropoxyphenylboronic acid
CAS No.:225517-86-2
Molecular Formula:C9H11BO3
Molecular Weight:177.99
Hs Code.:
European Community (EC) Number:970-881-2
DSSTox Substance ID:DTXSID101277182
Mol file:225517-86-2.mol

Synonyms:2-Cyclopropoxyphenylboronic acid;225517-86-2;(2-Cyclopropoxyphenyl)boronic acid;(2-cyclopropyloxyphenyl)boronic acid;Boronic acid, [2-(cyclopropyloxy)phenyl]-;MFCD16996192;SCHEMBL2405931;(2-Cyclopropoxyphenyl)boronicacid;VBEGXBKJOHNRNH-UHFFFAOYSA-N;DTXSID101277182;AKOS027263812;AT13884;MB20156;B-[2-(Cyclopropyloxy)phenyl]boronic acid;BS-16241;DA-07930;SY269088;CS-0135493;EN300-2585777;J-509249;Z1255389441

Suppliers and Price of 2-Cyclopropoxyphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Chemenu
(2-Cyclopropoxyphenyl)boronicacid 95%+
5g
$ 1030.00

Ambeed
(2-Cyclopropoxyphenyl)boronicacid 95+%
5g
$ 469.00

Ambeed
(2-Cyclopropoxyphenyl)boronicacid 95+%
1g
$ 135.00

Ambeed
(2-Cyclopropoxyphenyl)boronicacid 95+%
250mg
$ 55.00

Ambeed
(2-Cyclopropoxyphenyl)boronicacid 95+%
100mg
$ 38.00

AK Scientific
2-Cyclopropoxyphenylboronicacid
1g
$ 923.00

Total 6 raw suppliers

Chemical Property of 2-Cyclopropoxyphenylboronic acid

Chemical Property:

Boiling Point:363.9±44.0 °C(Predicted)
PKA:8.58±0.53(Predicted)
PSA：49.69000
Density:1.23±0.1 g/cm3(Predicted)
LogP:-0.09240
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:178.0801244
Heavy Atom Count:13
Complexity:170

Purity/Quality:

98% ^*data from raw suppliers

(2-Cyclopropoxyphenyl)boronicacid 95%+ ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=CC=C1OC2CC2)(O)O

Technology Process of 2-Cyclopropoxyphenylboronic acid

There total 3 articles about 2-Cyclopropoxyphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 121-43-7,63156-11-6
Trimethyl borate

: 38380-86-8
1-bromo-2-cyclopropoxybenzene

: 225517-86-2
2-cyclopropoxyphenylboronic acid

Guidance literature:: 1-bromo-2-cyclopropoxybenzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃;

Reference yield:

: trichlorooxybis(triphenylphosphine)rhenium

: 38380-86-8
1-bromo-2-cyclopropoxybenzene

: 225517-86-2
2-cyclopropoxyphenylboronic acid

Guidance literature:

Reference yield:

: 95-56-7
2-hydroxybromobenzene

: 225517-86-2
2-cyclopropoxyphenylboronic acid

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 2 h / 140 °C / Microwave irradiation; Sealed tube

2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

2.2: -78 - 20 °C

With n-butyllithium; potassium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide;