Benzoic acid, 2-[nitroso[3-(trifluoromethyl)phenyl]amino]-

Base Information

Chemical Name:Benzoic acid, 2-[nitroso[3-(trifluoromethyl)phenyl]amino]-
CAS No.:23595-00-8
Molecular Formula:C₁₄H₉F₃N₂O₃
Molecular Weight:310.232
Hs Code.:2922499990
Mol file:23595-00-8.mol

Synonyms:Anthranilicacid, N-nitroso-N-(a,a,a-trifluoro-m-tolyl)- (8CI); ITF 611;N-(m-Trifluoromethylphenyl)-N-nitrosoanthranilic acid;N-Nitroso-N-(3-trifluoromethylphenyl)anthranilic acid;N-Nitroso-N-(m-trifluoromethylphenyl)anthranilic acid

Suppliers and Price of Benzoic acid, 2-[nitroso[3-(trifluoromethyl)phenyl]amino]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of Benzoic acid, 2-[nitroso[3-(trifluoromethyl)phenyl]amino]-

Chemical Property:

Vapor Pressure:2.7E-09mmHg at 25°C
Boiling Point:461°Cat760mmHg
Flash Point:232.6°C
PSA：69.97000
Density:1.39g/cm³
LogP:4.22310

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 2-[nitroso[3-(trifluoromethyl)phenyl]amino]-

There total 5 articles about Benzoic acid, 2-[nitroso[3-(trifluoromethyl)phenyl]amino]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1404220-55-8
N-tert-butyl-2-(3-(trifluoromethyl)phenylamino)benzamide

: 23595-00-8
2-[nitroso(3-(trifluoromethyl)phenyl)amino]benzoic acid

Guidance literature:: With acetic anhydride; acetic acid; sodium nitrite; at 0 ℃; for 3h;
DOI:10.1002/anie.201205723

Reference yield:

: 98-88-4
benzoyl chloride

: 23595-00-8
2-[nitroso(3-(trifluoromethyl)phenyl)amino]benzoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane / 5 h / 0 - 20 °C / Inert atmosphere

2: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver hexafluoroantimonate / 1,2-dichloro-ethane / 24 h / 85 °C

3: acetic acid; acetic anhydride; sodium nitrite / 3 h / 0 °C

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; acetic anhydride; acetic acid; triethylamine; sodium nitrite; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1002/anie.201205723

Reference yield:

: 1423-26-3
(meta-(trifluoromethyl)phenyl)boronic acid

: 23595-00-8
2-[nitroso(3-(trifluoromethyl)phenyl)amino]benzoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: sodium azide; copper diacetate / methanol / 3 h / 55 °C

2: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver hexafluoroantimonate / 1,2-dichloro-ethane / 24 h / 85 °C

3: acetic acid; acetic anhydride; sodium nitrite / 3 h / 0 °C

With silver hexafluoroantimonate; sodium azide; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper diacetate; acetic anhydride; acetic acid; sodium nitrite; In methanol; 1,2-dichloro-ethane;
DOI:10.1002/anie.201205723