1-Bromo-4-iodo-2-(trifluoromethyl)benzene

Base Information

Chemical Name:1-Bromo-4-iodo-2-(trifluoromethyl)benzene
CAS No.:364-11-4
Molecular Formula:C7H3BrF3I
Molecular Weight:350.905
Hs Code.:2903999090
European Community (EC) Number:696-214-2
DSSTox Substance ID:DTXSID50479681
Nikkaji Number:J2.607.547E
Wikidata:Q72445768
Mol file:364-11-4.mol

Synonyms:1-Bromo-4-iodo-2-(trifluoromethyl)benzene;364-11-4;2-Bromo-5-iodobenzotrifluoride;1-Bromo-4-iodo-2-trifluoromethylbenzene;1-Bromo-4-iodo-2-trifluoromethyl benzene;MFCD11855999;SCHEMBL2299351;DTXSID50479681;AMY40732;AKOS014184722;PS-6996;SY018873;CS-0113118;FT-0746504;EN300-7361672;A874355

Suppliers and Price of 1-Bromo-4-iodo-2-(trifluoromethyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1-Bromo-4-iodo-2-trifluoromethylbenzene
100mg
$ 45.00

SynQuest Laboratories
2-Bromo-5-iodobenzotrifluoride
25 g
$ 124.00

SynQuest Laboratories
2-Bromo-5-iodobenzotrifluoride
1 g
$ 16.00

SynQuest Laboratories
2-Bromo-5-iodobenzotrifluoride
5 g
$ 40.00

Oakwood
2-Bromo-5-iodobenzotrifluoride 98%
5g
$ 34.00

Matrix Scientific
1-Bromo-4-iodo-2-trifluoromethyl benzene 95%
25g
$ 518.00

Matrix Scientific
1-Bromo-4-iodo-2-trifluoromethyl benzene 95%
5g
$ 260.00

Crysdot
1-Bromo-4-iodo-2-(trifluoromethyl)benzene 97%
25g
$ 132.00

Apolloscientific
2-Bromo-5-iodobenzotrifluoride
5g
$ 37.00

Apolloscientific
2-Bromo-5-iodobenzotrifluoride
1g
$ 15.00

Total 40 raw suppliers

Chemical Property of 1-Bromo-4-iodo-2-(trifluoromethyl)benzene

Chemical Property:

Melting Point:78-80℃ (water )
Boiling Point:245.1±35.0℃ (760 Torr)
Flash Point:102.1±25.9℃
PSA：0.00000
Density:2.176±0.06 g/cm3 (20 oC 760 Torr)
LogP:4.07250
Storage Temp.:Room temperature.
XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:349.84149
Heavy Atom Count:12
Complexity:159

Purity/Quality:

97% ^*data from raw suppliers

1-Bromo-4-iodo-2-trifluoromethylbenzene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=C(C=C1I)C(F)(F)F)Br

Technology Process of 1-Bromo-4-iodo-2-(trifluoromethyl)benzene

There total 7 articles about 1-Bromo-4-iodo-2-(trifluoromethyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 393-36-2
4-bromo-3-(trifluoromethyl)aniline

: 364-11-4
1-bromo-4-iodo-2-(trifluoromethyl)benzene

Guidance literature:: 4-bromo-3-(trifluoromethyl)aniline; With sulfuric acid; water; at -10 ℃;

With copper; potassium iodide; sodium nitrite; In water; at -8 - 102 ℃; for 2.16667h;

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 76-05-1
trifluoroacetic acid

: 364-11-4
1-bromo-4-iodo-2-(trifluoromethyl)benzene

: 364-12-5
4-bromo-1-iodo-2-(trifluoromethyl)benzene

Guidance literature:: With dipotassium peroxodisulfate; sodium carbonate; silver carbonate; In acetonitrile; at 120 ℃; for 10h; Schlenk technique;
DOI:10.1021/ol503189j

Reference yield:

: 392-83-6
o-trifluoromethylphenyl bromide

: 364-11-4
1-bromo-4-iodo-2-(trifluoromethyl)benzene

Guidance literature:: Multi-step reaction with 3 steps

1: sulfuric acid; fuming nitric acid

2: SnCl₂; aq.-ethanolic HCl

3: aqueous sulfuric acid; sodium nitrite / Erwaermen der Reaktionsloesung mit Kaliumjodid und Kupfer-Pulver

With hydrogenchloride; sulfuric acid; nitric acid; tin(ll) chloride; sodium nitrite;
DOI:10.1021/ja01152a111