N-phenyl-4-triMethylsilylaniline

Base Information

• Chemical Name: N-phenyl-4-triMethylsilylaniline
• CAS No.: 13024-18-5
• Molecular Formula: C15H19NSi
• Molecular Weight: 241.408
• Mol file: 13024-18-5.mol

Synonyms:Diphenylamine, 4-(trimethylsilyl)- (7CI,8CI);

Chemical Property of N-phenyl-4-triMethylsilylaniline

Chemical Property:

• PSA: 12.03000
• LogP: 4.04840
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

N-Phenyl-4-(trimethylsilyl)aniline 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-phenyl-4-triMethylsilylaniline

There total 3 articles about N-phenyl-4-triMethylsilylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1-bromo-4-(trimethylsilyl)benzene (6999-03-7) + aniline (62-53-3) → 4-(trimethylsilyl)-N-phenylbenzeneamine (13024-18-5)

Guidance literature:

1-bromo-4-(trimethylsilyl)benzene; aniline; With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene; for 3h; Heating / reflux;

With water; In tetrahydrofuran; toluene; at 20 ℃;

Reference yield: 76.0%

→ 4-(trimethylsilyl)-N-phenylbenzeneamine (13024-18-5)

Guidance literature:

With bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In toluene; at 95 ℃; for 4h;

Reference yield: 75.0%

4-chlorophenyltrimethylsilane (10557-71-8) + aniline (62-53-3) → 4-(trimethylsilyl)-N-phenylbenzeneamine (13024-18-5)

Guidance literature:

With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; In toluene; for 12h; Inert atmosphere; Reflux;

upstream raw materials:

1-bromo-4-(trimethylsilyl)benzene

aniline

4-chlorophenyltrimethylsilane

Downstream raw materials:

C₄₀H₄₂N₂Si₂

C₅₉H₅₂N₂Si₂

N-((4-trimethylsilyl)phenyl)-N-phenyl-4-((4-aminostyryl)-2-cyano)-3-phenylacrylic acid