2-Bromo-6-(bromomethyl)naphthalene

Base Information

• Chemical Name: 2-Bromo-6-(bromomethyl)naphthalene
• CAS No.: 305798-02-1
• Molecular Formula: C11H8Br2
• Molecular Weight: 299.993
• Hs Code.: 2903999090
• DSSTox Substance ID: DTXSID90599650
• Wikidata: Q82495563
• Mol file: 305798-02-1.mol

Synonyms:2-BROMO-6-(BROMOMETHYL)NAPHTHALENE;305798-02-1;NAPHTHALENE,2-BROMO-6-(BROMOMETHYL)-;SCHEMBL4696760;DTXSID90599650;2-bromo-6-(bromomethyl) naphthalene;MFCD09842471;AKOS015966432;DS-6331;DB-364858;O10686;EN300-3091976

Chemical Property of 2-Bromo-6-(bromomethyl)naphthalene

Chemical Property:

• PSA: 0.00000
• LogP: 4.49720
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 299.89723
• Heavy Atom Count: 13
• Complexity: 170

Purity/Quality:

97% ^*data from raw suppliers

2-Bromo-6-(bromomethyl)naphthalene 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C=CC(=C2)Br)C=C1CBr

Technology Process of 2-Bromo-6-(bromomethyl)naphthalene

There total 4 articles about 2-Bromo-6-(bromomethyl)naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.2%

(6-bromo-2-naphthy)methanol (100751-63-1) → 2-bromo-6-(bromomethyl)naphthalene (305798-02-1)

Guidance literature:

With phosphorus tribromide; In chloroform; at 20 ℃; for 1h;

Reference yield:

2-bromo-6-methylnaphthalene (37796-78-4) → 2-bromo-6-(bromomethyl)naphthalene (305798-02-1)

Guidance literature:

With bromine; at 210 ℃; Irradiation;

DOI:10.1021/ja01189a002

Reference yield:

6-methylnaphthalen-2-amine (37796-79-5) → 2-bromo-6-(bromomethyl)naphthalene (305798-02-1)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous HBr / Diazotization_.Behandlung der Diazoniumsalz-Loesung mit CuBr in wss. HBr bei 70-80grad

2: bromine / 210 °C / Irradiation

With hydrogen bromide; bromine;

DOI:10.1021/ja01189a002

upstream raw materials:

2-bromo-6-methylnaphthalene

6-methylnaphthalen-2-amine

(6-bromo-2-naphthy)methanol

Downstream raw materials:

2-(6-bromonaphthalen-2-yl)acetic acid

2-((6-bromonaphthalen-2-yl)methyl)-2-(1-phenylbut-3-en-1-yl)malononitrile

2-allyl-2-(2-(6-bromonaphthalen-2-yl)-1-phenylethyl)malononitrile

((6-bromonaphthalen-2-yl)methyl)tributylstannane