2-BroMo TriphenylaMine

Base Information

• Chemical Name: 2-BroMo TriphenylaMine
• CAS No.: 78600-31-4
• Molecular Formula: C18H14BrN
• Molecular Weight: 324.22
• Mol file: 78600-31-4.mol

Synonyms:Benzenamine, 2-bromo-N,N-diphenyl-

Chemical Property of 2-BroMo TriphenylaMine

Chemical Property:

• Melting Point: 61.0 to 65.0 °C
• Boiling Point: 165°C/0.3mmHg(lit.)
• PKA: -3.76±0.18(Predicted)
• PSA: 3.24000
• Density: 1.369
• LogP: 5.91890
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: soluble in Toluene

Purity/Quality:

99% ^*data from raw suppliers

2-Bromo-N,N-diphenylaniline ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-BroMo TriphenylaMine

There total 3 articles about 2-BroMo TriphenylaMine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.7%

1-Bromo-2-iodobenzene (583-55-1) + diphenylamine (122-39-4) → N-(2-bromophenyl)-N-phenylbenzenamine (78600-31-4)

Guidance literature:

With potassium carbonate; copper dichloride; In dimethyl sulfoxide; for 12h; Reflux;

Reference yield: 73.0%

diphenylamine (122-39-4) + 2,3-dibromobenzene (583-53-9) → N-(2-bromophenyl)-N-phenylbenzenamine (78600-31-4)

Guidance literature:

With copper(l) iodide; 18-crown-6 ether; In 1,2-dichloro-benzene; at 100 - 210 ℃; Inert atmosphere; Darkness;

Reference yield: 69.0%

→ N-(2-bromophenyl)-N-phenylbenzenamine (78600-31-4)

Guidance literature:

With triethanolamine; tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; In toluene; for 16h; Reflux;

upstream raw materials:

1-Bromo-2-iodobenzene

diphenylamine

2,3-dibromobenzene

Downstream raw materials:

3'-bromo-10-phenyl-10H-spiro(acridine-9,9'-fluorene)

Refernces

• 1、 Li, Huanhuan,Wang, Yang,Yuan, Kai,Tao, Ye,Chen, Runfeng,Zheng, Chao,Zhou, Xinhui,Li, Junfeng,Huang, Wei. "Efficient synthesis of π-extended phenazasilines for optical and electronic applications". . p. 15760 - 15763. Retrieved 2014.
• 2、 Kang, Seokwoo,Jung, Hyocheol,Lee, Hayoon,Park, Sunwoo,Kim, Joonghan,Park, Jongwook. "Highly efficient dual-core derivatives with EQEs as high as 8.38% at high brightness for OLED blue emitters". . p. 14709 - 14716. Retrieved 2019/12/06.
• 3、 -. "COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE DEVICES, ORGANIC ELECTROLUMINESCENCE DEVICE, AND ELECTRONIC DEVICE". Paragraph 0204. . Retrieved 2018/07/15.