B-[1,1':3',1''-Terphenyl]-3-ylboronic acid

Base Information

Chemical Name:B-[1,1':3',1''-Terphenyl]-3-ylboronic acid
CAS No.:934603-99-3
Molecular Formula:C18H15BO2
Molecular Weight:274.127
Hs Code.:
Mol file:934603-99-3.mol

Synonyms:m-terphenyl-3-boronicacid;1,1':3',1''-Terphenyl-3-ylboronic acid;B-[1,1':3',1''-Terphenyl]-3-ylboronic acid;Boronic acid, B-?[1,?1':3',?1''-?terphenyl]?-?3-?yl-

Suppliers and Price of B-[1,1':3',1''-Terphenyl]-3-ylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 25 raw suppliers

Chemical Property of B-[1,1':3',1''-Terphenyl]-3-ylboronic acid

Chemical Property:

Boiling Point:506℃
PKA:8.29±0.10(Predicted)
Flash Point:260℃
PSA：40.46000
Density:1.21
LogP:2.70040

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of B-[1,1':3',1''-Terphenyl]-3-ylboronic acid

There total 3 articles about B-[1,1':3',1''-Terphenyl]-3-ylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 5419-55-6
Triisopropyl borate

: 98905-03-4
3-bromo-1,1′: 3′1″-terphenyl

: 934603-99-3
B-[1,1′:3′,1″-terphenyl]-3-ylboronic acid

Guidance literature:: 3-bromo-1,1′: 3′1″-terphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;

Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

With hydrogenchloride; water; In tetrahydrofuran; hexane; at 20 ℃; for 1h; Inert atmosphere;

Reference yield:

: 5122-95-2
3-Biphenylboronic acid

: 934603-99-3
B-[1,1′:3′,1″-terphenyl]-3-ylboronic acid

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; 1,2-dimethoxyethane; water / 10 h / Inert atmosphere; Reflux

2.1: n-butyllithium / hexane; tetrahydrofuran / -78 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

2.3: 1 h / 20 °C / Inert atmosphere

With n-butyllithium; sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; water; toluene;

Reference yield:

: 591-18-4
1-Bromo-3-iodobenzene

: 934603-99-3
B-[1,1′:3′,1″-terphenyl]-3-ylboronic acid

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium carbonate / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; 1,2-dimethoxyethane; water / 10 h / Inert atmosphere; Reflux

2.1: n-butyllithium / hexane; tetrahydrofuran / -78 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

2.3: 1 h / 20 °C / Inert atmosphere

With n-butyllithium; sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; water; toluene;