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5122-95-2

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5122-95-2 Usage

Uses

Different sources of media describe the Uses of 5122-95-2 differently. You can refer to the following data:
1. 3-Biphenylboronic Acid is a fluorescent boronic acid useful for sensitive detection of sugars in water.
2. suzuki reaction
3. It is a biological reagent used as a boronate-assisted fluorogenic chemosensor. It is evaluated for pharmacological activity as fatty acid amide hydrolase inhibitors. It is a reactant involved in coupling with potassium cyanate, quinones, or fluorous tagged N-hydroxyphthalimide and direct C-H arylation of electron-deficient heterocycles.
4. Biological reagent used as a boronate-assisted fluorogenic chemosensorEvaluated for pharmacological activity as fatty acid amide hydrolase inhibitorsReactant involved in:Coupling with potassium cyanate, quinones, or fluorous tagged N-hydroxyphthalimideDirect C-H arylation of electron-deficient heterocycles

Chemical Properties

yellow crystal powder

Check Digit Verification of cas no

The CAS Registry Mumber 5122-95-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,1,2 and 2 respectively; the second part has 2 digits, 9 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 5122-95:
(6*5)+(5*1)+(4*2)+(3*2)+(2*9)+(1*5)=72
72 % 10 = 2
So 5122-95-2 is a valid CAS Registry Number.
InChI:InChI=1/C12H11BO2/c14-13(15)12-8-4-7-11(9-12)10-5-2-1-3-6-10/h1-9,14-15H

5122-95-2 Well-known Company Product Price

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  • TCI America

  • (B2489)  3-Biphenylboronic Acid (contains varying amounts of Anhydride)  

  • 5122-95-2

  • 5g

  • 480.00CNY

  • Detail
  • TCI America

  • (B2489)  3-Biphenylboronic Acid (contains varying amounts of Anhydride)  

  • 5122-95-2

  • 25g

  • 1,480.00CNY

  • Detail
  • Alfa Aesar

  • (L17552)  Biphenyl-3-boronic acid, 98%   

  • 5122-95-2

  • 1g

  • 396.0CNY

  • Detail
  • Alfa Aesar

  • (L17552)  Biphenyl-3-boronic acid, 98%   

  • 5122-95-2

  • 5g

  • 1238.0CNY

  • Detail

5122-95-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name Biphenyl-3-boronic acid

1.2 Other means of identification

Product number -
Other names 3-Biphenylboronic

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5122-95-2 SDS

5122-95-2Synthetic route

Trimethyl borate
121-43-7

Trimethyl borate

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-bromobiphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #2: Trimethyl borate In tetrahydrofuran at -78 - 20℃;
Stage #3: With hydrogenchloride In tetrahydrofuran at 20℃; for 2h; Further stages.;
75%
With hydrogenchloride; n-butyllithium In tetrahydrofuran soln. of n-BuLi in hexanes added dropwise to soln. of biphenyl compd. at-78°C under Ar, kept at this temp. for 2 h, soln. of borate adde d over 30 min, allowed to warm to room temp. overnight, 10% aq. HCl added, stirred for 2 h at room temp.; extd. into Et2O, washed with concd. soln. of Na2CO3 then with H2O, evapd., recrystd. twice from H2O/EtOH (95/5);75%
Stage #1: 3-bromobiphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane for 24h;
65%
With hydrogenchloride; n-butyllithium In tetrahydrofuran; hexane BuLi soln. (hexane) addn. to biphenylbromide soln. (THF), mixt. stirring1 h, mixt. addn. to B-compd. soln. (THF) via canula (N2) at -78° C., stirring 1 h, gradual warming to room temp., aq. HCl addn., stirringat room temp. 15 h, solvent removal; under reduced pressure, Et2O addn., org. layer sepn., drying (MgSO4), soln. concn.. oil triturating with hexane, solid repptn. from MeOH/H2O;43%
With hydrogenchloride; tert.-butyl lithium In water; pentane
3-bromobiphenyl
2113-57-7

3-bromobiphenyl

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-bromobiphenyl With n-butyllithium In tetrahydrofuran; hexane at -80℃; for 1h; Inert atmosphere;
Stage #2: With Trimethyl borate In tetrahydrofuran; hexane at -80 - 20℃; for 4h;
Stage #3: With hydrogenchloride; water In tetrahydrofuran; hexane for 2h;
55%
Multi-step reaction with 2 steps
1.1: n-BuLi / -78 °C
1.2: -78 - 20 °C
2.1: aq. HCl
View Scheme
Stage #1: 3-bromobiphenyl With magnesium In tetrahydrofuran
Stage #2: With Trimethyl borate
Stage #3: With hydrogenchloride Further stages.;
Trimethyl borate
121-43-7

Trimethyl borate

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride; n-butyllithium In tetrahydrofuran; hexane BuLi soln. (hexane) addn. to biphenylbromide soln. (THF), mixt. stirring1 h, mixt. addn. to B-compd. soln. (THF) via canula (N2) at -78° C., stirring 1 h, gradual warming to room temp., aq. HCl addn., stirringat room temp. 15 h, solvent removal; under reduced pressure, Et2O addn., org. layer sepn., drying (MgSO4), soln. concn.. oil triturating with hexane, solid repptn. from MeOH/H2O;40%
boric acid tributyl ester
688-74-4

boric acid tributyl ester

[(1,1'-biphenyl)-3-yl]magnesium bromide
103068-18-4

[(1,1'-biphenyl)-3-yl]magnesium bromide

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
With diethyl ether at -70℃; und anschliessenden Hydrolyse;
C18H23BO2

C18H23BO2

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: Pd(PPh3)4; Na2CO3 / 1,2-dimethoxy-ethane / 80 °C
2.1: n-BuLi / -78 °C
2.2: -78 - 20 °C
3.1: aq. HCl
View Scheme
Multi-step reaction with 2 steps
1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol / 3 h / 90 °C
2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere
2.2: 24 h
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

polymer; monomer(s): Actitex 1500-1, modified with [BF4][4-N2C6H4CH2Cl]; 4-halogenobenzenethiol

polymer; monomer(s): Actitex 1500-1, modified with [BF4][4-N2C6H4CH2Cl]; 4-halogenobenzenethiol

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: Pd(PPh3)4; Na2CO3 / 1,2-dimethoxy-ethane / 80 °C
2.1: n-BuLi / -78 °C
2.2: -78 - 20 °C
3.1: aq. HCl
View Scheme
Triisopropyl borate
5419-55-6

Triisopropyl borate

3-bromobiphenyl
2113-57-7

3-bromobiphenyl

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
Stage #1: 3-bromobiphenyl With n-butyllithium In diethyl ether; hexane; toluene at -30 - 0℃; for 1h;
Stage #2: Triisopropyl borate In diethyl ether; hexane; toluene at -70 - 20℃; for 1h;
Stage #3: With hydrogenchloride; water In diethyl ether; hexane; toluene
With tert.-butyl lithium In diethyl ether; pentane
phenylboronic acid
98-80-6

phenylboronic acid

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; ethanol / 3 h / 90 °C
2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere
2.2: 24 h
View Scheme
9-bromo-N-(tert-butyl)-3,4-dihydro-2H,6H-pyrimido[1,2-c][1,3]benzothiazin-6-imine
1394235-81-4

9-bromo-N-(tert-butyl)-3,4-dihydro-2H,6H-pyrimido[1,2-c][1,3]benzothiazin-6-imine

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

9-[(1-1’-biphenyl)-3-yl]-N-(tert-butyl)-3,4-dihydro-2H,6H-pyrimido[1,2-c][1,3]benzothiazin-6-imine
1410123-84-0

9-[(1-1’-biphenyl)-3-yl]-N-(tert-butyl)-3,4-dihydro-2H,6H-pyrimido[1,2-c][1,3]benzothiazin-6-imine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In ethanol; water; toluene for 1h; Suzuki-Miyaura Coupling; Reflux;100%
2-chloro-4,5-dimethoxypyrimidine
1333240-17-7

2-chloro-4,5-dimethoxypyrimidine

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

2-(3-biphenyl)-4,5-dimethoxypyrimidine

2-(3-biphenyl)-4,5-dimethoxypyrimidine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane; water for 8h; Suzuki Coupling; Reflux; Inert atmosphere;100%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

C25H27N3O3

C25H27N3O3

C35H31N3O

C35H31N3O

Conditions
ConditionsYield
Stage #1: C25H27N3O3 With trichlorophosphate In toluene at 100℃; for 0.5h; Microwave irradiation;
Stage #2: 3-Biphenylboronic acid With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In 1,4-dioxane at 90℃; for 16h;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 20℃;
100%
methyl o-formylbenzoate
4122-56-9

methyl o-formylbenzoate

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

3-(biphenyl-3-yl)-3H-isobenzofuran-1-one
1196466-84-8

3-(biphenyl-3-yl)-3H-isobenzofuran-1-one

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); C27H30N2S(1+)*Cl(1-); cesium fluoride In toluene at 80℃; for 1h; Inert atmosphere;99%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

2,4,6-tris(biphenyl-3-yl)boroxine
1448354-51-5

2,4,6-tris(biphenyl-3-yl)boroxine

Conditions
ConditionsYield
In toluene for 2h; Reflux; Dean-Stark; Inert atmosphere;99%
In toluene for 1h; Reflux; Molecular sieve;
bromochlorobenzene
106-39-8

bromochlorobenzene

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

4-chloro-[1,1':3',1

4-chloro-[1,1':3',1"]terphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 70℃; for 8h; Inert atmosphere;99%
Stage #1: bromochlorobenzene; 3-Biphenylboronic acid In ethanol; toluene Inert atmosphere;
Stage #2: With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 70℃; for 8h; Inert atmosphere;
99%
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In 1,2-dimethoxyethane; water for 4h; Inert atmosphere; Reflux;4.11 g
but-3-enoic acid
625-38-7

but-3-enoic acid

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

4-([1,1'-biphenyl]-3-yl)butanoic acid
25663-67-6

4-([1,1'-biphenyl]-3-yl)butanoic acid

Conditions
ConditionsYield
With propan-1-ol; bis(1,5-cyclooctadiene)nickel (0); potassium tert-butylate; 4,4-dibenzyl-2-(pyridin-2-yl)-4,5-dihydrooxazole at 60℃; Sealed tube; regioselective reaction;99%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

3-bromo-4-chloropyrazolo<3,4-d>pyrimidine
90914-41-3

3-bromo-4-chloropyrazolo<3,4-d>pyrimidine

3-chloro-aniline
108-42-9

3-chloro-aniline

(3-biphenyl-3-yl-1H-pyrazolo[3,4-d]pyrimidin-4-yl)-(3-chloro-phenyl)-amine

(3-biphenyl-3-yl-1H-pyrazolo[3,4-d]pyrimidin-4-yl)-(3-chloro-phenyl)-amine

Conditions
ConditionsYield
Stage #1: 3-bromo-4-chloropyrazolo<3,4-d>pyrimidine; 3-chloro-aniline With acetic acid In 1,4-dioxane at 150℃; for 0.166667h; microwave irradiation;
Stage #2: 3-Biphenylboronic acid With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In 1,4-dioxane at 180℃; for 0.166667h; Suzuki coupling; microwave irradiation;
98%
C19H9F17N2O4
1239023-23-4

C19H9F17N2O4

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

C31H17F17N2O4
1239023-83-6

C31H17F17N2O4

Conditions
ConditionsYield
With pyridine; oxygen; copper diacetate In α,α,α-trifluorotoluene at 20℃; for 48h;98%
C21H10Cl2N4S
1420118-37-1

C21H10Cl2N4S

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

C33H19ClN4S
1420118-43-9

C33H19ClN4S

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; toluene at 120℃; for 5h;98%
2-(4-fluorophenyl)-3-iodo-6-phenylimidazo[1,2-a]pyridine
1443986-18-2

2-(4-fluorophenyl)-3-iodo-6-phenylimidazo[1,2-a]pyridine

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

3-(biphenyl-3-yl)-2-(4-fluorophenyl)-6-phenylimidazo[1,2-a]pyridine
1443985-68-9

3-(biphenyl-3-yl)-2-(4-fluorophenyl)-6-phenylimidazo[1,2-a]pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 100℃; for 4h; Suzuki Coupling; Inert atmosphere;98%
methyl 4-((N-(4-bromophenyl)morpholine-4-carboxamido)methyl)benzoate

methyl 4-((N-(4-bromophenyl)morpholine-4-carboxamido)methyl)benzoate

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

methyl 4-((N-(4-(biphenyl-3-yl)phenyl)morpholine-4-carboxamido)methyl)benzoate

methyl 4-((N-(4-(biphenyl-3-yl)phenyl)morpholine-4-carboxamido)methyl)benzoate

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In 1,4-dioxane; water at 100℃; for 6h;98%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate
135654-49-8

diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate

1,3-diphenylbenzene
92-06-8

1,3-diphenylbenzene

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); sodium hydrogencarbonate In N,N-dimethyl-formamide at 60℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; Sealed tube;98%
(5-bromothiazol-2-yl)methylcarbamic acid tert-butyl ester
713107-42-7

(5-bromothiazol-2-yl)methylcarbamic acid tert-butyl ester

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

tert-butyl ((5-([1,1'-biphenyl]-3-yl)thiazol-2-yl)methyl)carbamate

tert-butyl ((5-([1,1'-biphenyl]-3-yl)thiazol-2-yl)methyl)carbamate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,2-dimethoxyethane; water at 100℃; for 18h; Inert atmosphere;98%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

C9H12NO2(1+)*CF3O3S(1-)

C9H12NO2(1+)*CF3O3S(1-)

C21H21NO2

C21H21NO2

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; sodium carbonate; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl In 1,4-dioxane; water at 80℃; for 2h; enantioselective reaction;98%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

5-bromo-2-(5-bromo-3-(5H-dibenzo[b,d]borapentadien-5-yl)thien-2-yl)pyridine

5-bromo-2-(5-bromo-3-(5H-dibenzo[b,d]borapentadien-5-yl)thien-2-yl)pyridine

C45H30BNS

C45H30BNS

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate In water; toluene at 110℃; for 24h; Inert atmosphere;98%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

sodium methansulfinate
20277-69-4

sodium methansulfinate

3-(methanesulfonyl)-1,1'-biphenyl
31477-45-9

3-(methanesulfonyl)-1,1'-biphenyl

Conditions
ConditionsYield
With copper diacetate; 4 Angstroem MS; potassium carbonate In dimethyl sulfoxide at 20℃; for 16h;97%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

9-chloro-3-methoxy-11-phenylbenzo[a]carbazole

9-chloro-3-methoxy-11-phenylbenzo[a]carbazole

9-([1,1'-biphenyl]-3-yl)-3-methoxy-11-phenylbenzo[a]carbazole

9-([1,1'-biphenyl]-3-yl)-3-methoxy-11-phenylbenzo[a]carbazole

Conditions
ConditionsYield
With potassium phosphate; bis(dibenzylideneacetone)-palladium(0); tricyclohexylphosphine In water; toluene for 7h; Suzuki Coupling; Inert atmosphere; Reflux;97%
2-bromo-9H-fluorene
1133-80-8

2-bromo-9H-fluorene

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

C25H18

C25H18

Conditions
ConditionsYield
With C35H40N4O9(2+)*2Cl(1-); palladium diacetate; potassium hydroxide In ethanol at 100℃; for 1.5h; Suzuki Coupling; Green chemistry;97%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

1-iodo-2-((2-methylallyl)oxy)benzene
156642-47-6

1-iodo-2-((2-methylallyl)oxy)benzene

(R)-3-([1,1'-biphenyl]-3-ylmethyl)-3-methyl-2,3-dihydrobenzofuran

(R)-3-([1,1'-biphenyl]-3-ylmethyl)-3-methyl-2,3-dihydrobenzofuran

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); (R)-N-((S)-(3,5-di-tert-butyl-4-methoxyphenyl)(2-(dicyclohexylphosphanyl)phenyl)methyl)-N,2-dimethylpropane-2-sulfinamide; potassium hydroxide In toluene at 20 - 85℃; Inert atmosphere; Sealed tube; enantioselective reaction;97%
1-Bromo-3-iodobenzene
591-18-4

1-Bromo-3-iodobenzene

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

3-bromo-1,1′: 3′1″-terphenyl
98905-03-4

3-bromo-1,1′: 3′1″-terphenyl

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; toluene for 8h; Suzuki Coupling; Heating / reflux;96%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water; toluene for 10h; Inert atmosphere; Reflux;93%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 6h; Inert atmosphere;91%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

C24H14Br2N2

C24H14Br2N2

C48H32N2

C48H32N2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;96%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran at 80℃; for 12h; Inert atmosphere;96%
N-methyl-N-(2-formylphenyl)but-2-ynamide

N-methyl-N-(2-formylphenyl)but-2-ynamide

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

3-(1-([1,1'-biphenyl]-3-yl)-1-hydroxyethyl)-1-methylquinolin-2(1H)-one

3-(1-([1,1'-biphenyl]-3-yl)-1-hydroxyethyl)-1-methylquinolin-2(1H)-one

Conditions
ConditionsYield
With [(dppe)Pd(H2O)2](OTf)2 In 1,4-dioxane; water at 30 - 35℃; for 6h;96%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

2-(acetylamino)-5-benzyl-3-bromopyridine N-oxide
130276-95-8

2-(acetylamino)-5-benzyl-3-bromopyridine N-oxide

2-(acetylamino)-5-benzyl-3-(3-biphenylyl)pyridine N-oxide
130276-96-9

2-(acetylamino)-5-benzyl-3-(3-biphenylyl)pyridine N-oxide

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 90 - 95℃; for 17h;95%
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

5-Bromo-2,2-dimethoxyindane-1,3-dione
160775-51-9

5-Bromo-2,2-dimethoxyindane-1,3-dione

5-Biphenyl-3-yl-2,2-dimethoxy-indan-1,3-dione
160775-69-9

5-Biphenyl-3-yl-2,2-dimethoxy-indan-1,3-dione

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; benzene for 6h; Heating;95%
para-bromotoluene
106-38-7

para-bromotoluene

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

4-methyl-(1,1',3',1'')-terphenyl

4-methyl-(1,1',3',1'')-terphenyl

Conditions
ConditionsYield
With caesium carbonate; bis(η3-allyl-μ-chloropalladium(II)) In 1,4-dioxane at 90℃; for 20h; Suzuki-Miyaura cross-coupling reaction;95%
3-(4-bromophenyl)-1-(pyridin-2-yl)-1H-pyrazol-5-yl t-butyl carbonate
1270083-94-7

3-(4-bromophenyl)-1-(pyridin-2-yl)-1H-pyrazol-5-yl t-butyl carbonate

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

tert-butyl 1-(2-pyridinyl)-3-[4-(3'-phenyl)biphenyl]-5-pyrazolyl carbonate
1270084-08-6

tert-butyl 1-(2-pyridinyl)-3-[4-(3'-phenyl)biphenyl]-5-pyrazolyl carbonate

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium phosphate In 1,4-dioxane at 100℃; for 1h; Suzuki-Miyaura cross-coupling;95%
1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

4-bromo-[1,1′;3′,1′′]-terphenyl
54590-37-3

4-bromo-[1,1′;3′,1′′]-terphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 8h; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 60℃; for 3h;93%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene at 120℃; for 24h;90%
2-(4-fluorophenyl)-3-iodo-6-(thien-3-yl)imidazo[1,2-a]pyridine
1443986-20-6

2-(4-fluorophenyl)-3-iodo-6-(thien-3-yl)imidazo[1,2-a]pyridine

3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

3-(biphenyl-3-yl)-2-(4-fluorophenyl)-6-(thien-3-yl)imidazo[1,2-a]pyridine
1443985-72-5

3-(biphenyl-3-yl)-2-(4-fluorophenyl)-6-(thien-3-yl)imidazo[1,2-a]pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 100℃; for 4h; Suzuki Coupling; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water Suzuki Coupling;
3-Biphenylboronic acid
5122-95-2

3-Biphenylboronic acid

N-(tert-butoxycarbonyl)-4-iodo-L-phenylalanine methyl ester
113850-76-3

N-(tert-butoxycarbonyl)-4-iodo-L-phenylalanine methyl ester

C27H29NO4
1487184-10-0

C27H29NO4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) Suzuki Coupling;95%

5122-95-2Relevant articles and documents

COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF

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Paragraph 0266; 0275; 0276, (2016/10/07)

The present invention provides a novel compound capable of improving light emitting efficiency, stability and lifespan of an element, an organic electronic element using the same and an electronic device thereof.(110) Substrate(120) Positive electrode(130) Hole injection layer(140) Hole transfer layer(141) Buffer layer(150) Light emitting layer(151) Light-emitting assisting layer(160) Electron transfer layer(170) Electron injection layer(180) Negative electrodeCOPYRIGHT KIPO 2016

CARBAZOLE DERIVATIVE, LIGHT-EMITTING ELEMENT MATERIAL, LIGHT-EMITTING ELEMENT, AND LIGHT-EMITTING DEVICE

-

Page/Page column 178-179, (2010/04/03)

ABSTRACT An object is to provide a carbazole derivative which has a wide band gap and with which excellent blue color purity is obtained. In addition, another object is to provide highly reliable light-emitting elements, light-emitting devices, lighting devices, and electronic devices in which the carbazole derivative is used. Carbazole derivatives represented by the general formulas (1), (P1), and (M1) are provided. Further, light-emitting elements, light-emitting devices, and electronic devices which are formed using the carbazole derivative represented any of the general formulas (1), (P1), and (M1) are provided.

Aromatic amine derivative and organic electroluminescence device employing the same

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Page/Page column 19, (2010/11/27)

A novel aromatic amine derivative having a specific structure and an organic electroluminescence device comprising an organic thin film layer which comprises at least one layer comprising at least a light emitting layer and is disposed between a cathode and an anode, wherein at least one layer in the organic thin film layer comprises the aromatic amine derivative singly or as a component of a mixture. The device can be driven under a decreased voltage and has a long life. The device can be realized by using the derivative.

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