(3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate

Base Information

Chemical Name:(3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate
CAS No.:31752-98-4
Molecular Formula:C₂₈H₂₆O₅
Molecular Weight:442.511
Hs Code.:
Mol file:31752-98-4.mol

Synonyms:(3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate

Suppliers and Price of (3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 20 raw suppliers

Chemical Property of (3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate

Chemical Property:

Boiling Point:629.1±55.0 °C(Predicted)
PSA：61.83000
Density:1.26±0.1 g/cm3(Predicted)
LogP:5.04740

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate

There total 3 articles about (3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxo-hexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 31752-99-5
(-)-Corey lactone 5-(4-phenylbenzoate)

: 100-39-0
benzyl bromide

: 31752-98-4,39265-56-0,42586-95-8,51262-72-7,54382-72-8,59598-57-1
(3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate

Guidance literature:: With 2,6-di-tert-butyl-pyridine; silver trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1016/0040-4039(94)88256-8

Reference yield:

: 31752-98-4,39265-56-0,42586-95-8,51262-72-7,54382-72-8,59598-57-1
Biphenyl-4-carboxylic acid (4R,5S)-4-benzyloxymethyl-2-oxo-hexahydro-cyclopenta[b]furan-5-yl ester

Guidance literature:: Hydroxyl-Derivat (VIII), p-Phenylbenzoesaeure;

Reference yield:

: 31752-98-4,39265-56-0,42586-95-8,51262-72-7,54382-72-8,59598-57-1
(3aR,4S,5R,6aS)-4-[(benzyloxy)methyl]-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl 4-phenylbenzoate

Guidance literature:: Verb. 15, 1. KOH, 2. HCl, 3. p-Toluolsulfonsaeure, 4. NaHCO3, H2O -> Hydroxylaceton, 5. p-Phenylbenzoesaeurechlorid, Pyridin;
DOI:10.1002/hlca.19750580228