(+)-Tris(1,10-phenanthroline)ruthenium(II)

Base Information

• Chemical Name: (+)-Tris(1,10-phenanthroline)ruthenium(II)
• CAS No.: 19368-51-5
• Molecular Formula: C36H24N6Ru+2
• Molecular Weight: 641.6849
• Mol file: 19368-51-5.mol

Synonyms:(+)-Tris(1,10-phenanthroline)ruthenium(II);(OC-6-11)-(+)-Tris(1,10-phenanthroline-N1,N10)ruthenium(2+);Ruthenium(2+), tris(1,10-phenanthroline-N1,N10)-, (OC-6-11)-(+)-;C36-H24-N6-Ru;(-)-Tris(1,10-phenanthroline)ruthenium(II);24162-09-2;C36H24N6Ru;C12H15NO6S.C11H12N2S;C12-H15-N-O6-S.C11-H12-N2-S;Tris(1,10-phenanthroline)ruthenium(2+) ion(-)-;Ruthenium(2+), tris(1,10-phenanthroline)-, ion(-)-

Chemical Property of (+)-Tris(1,10-phenanthroline)ruthenium(II)

Chemical Property:

• Vapor Pressure: 3.38E-05mmHg at 25°C
• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 164.8°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 642.110585
• Heavy Atom Count: 43
• Complexity: 183

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.[Ru+2]
• General Description: 1,10-Phenanthroline, ruthenium(2+) salt (3:1), also known as tris(1,10-phenanthroline)ruthenium(II) or Ru(phen)32?, is a luminescent complex characterized by a metal-to-ligand charge transfer (MLCT) excited state. Its photophysical properties, such as emission maxima and lifetimes, are influenced by interactions with micellar media, particularly cationic surfactants like DTAB, where premicellar aggregates lead to significant emission quenching and spectral changes. Compared to bps-containing analogs, Ru(phen)32? exhibits stronger interactions with micelles due to its reduced hydrophilicity, resulting in more pronounced alterations in its spectral behavior. These features make it a useful probe for studying electrostatic and hydrophobic interactions in surfactant systems.

Technology Process of (+)-Tris(1,10-phenanthroline)ruthenium(II)

There total 7 articles about (+)-Tris(1,10-phenanthroline)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,10-Phenanthroline (66-71-7) + ruthenium(III)chloride (10049-08-8,63767-78-2) → Ru(phen)32+ (24162-09-2,22873-66-1,19368-51-5)

Guidance literature:

With NH₂OH*HCl or Na arsenite; In not given; reduction of Ru(III) chloride with NH2OH*HCl in presence of phenanthroline; react. accelerated by increasing the temp. up to 100 °C; with Na arsenite as reducing agent slower reaction;;

DOI:10.1021/ac60130a004

Reference yield:

tris(2,2'-bipyridyl)cobalt(II) (15878-95-2) + tris(1,10-phenanthroline)ruthenium(III)(3+) (41673-52-3,23633-32-1,19694-32-7) → Ru(phen)32+ (24162-09-2,22873-66-1,19368-51-5) + tris(2,2'-bipyridyl)cobalt(III) (41587-80-8,41574-35-0,19052-39-2)

Guidance literature:

With lithium chloride; In water; acetonitrile; Irradiation (UV/VIS); flash photolysis; monitored by UV spectroscopy; Kinetics;

DOI:10.1021/ja00293a035

Reference yield:

[Ru(1,10-phenanthroline)2Cl2] + 1,10-Phenanthroline (66-71-7) → Ru(phen)32+ (24162-09-2,22873-66-1,19368-51-5)

Guidance literature:

In methanol; refluxing with excess ligand for a few h; addn. of water, followed by addn. of aq. NaClO4 or LiCl; filtration;

DOI:10.1021/ja00304a015

upstream raw materials:

1,10-Phenanthroline

ruthenium(III)chloride

tris(2,2'-bipyridyl)cobalt(II)

tris(1,10-phenanthroline)ruthenium(III)⁽³⁺⁾

Downstream raw materials:

tris(1,10-phenanthroline)ruthenium(III)⁽³⁺⁾

[fac-(rhenium(I))Cl(CO)3(bathocuproinedisulfonate)]^(2-)

Co(1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6]eicosane)⁽²⁺⁾