15878-95-2Relevant academic research and scientific papers
OXIDATION OF cis-DIALKYLCOBALT(III) COMPLEXES BY OXIGEN. ACTIVATION OF OXIGEN BY PERCHLORIC ACID
Fukuzumi, Shunichi,Ishikawa, Kunio,Tanaka, Toshio
, p. 1 - 4 (1986)
The effects of protons on the reactions of cis-dialkylcobalt(III) complexes, cis-ClO4 (R = Me, Et, PhCH2; bpy = 2,2'-bipyridine), with oxigen are reported.Oxigen is shown to be activated in the presence of perchloric acid by forming hydroperoxonium ion which has a much stronger oxidizing ability than oxigen.
Electron-Transfer Reactions of Re(CO)5: Atom-Transfer-Concerted Mechanism vs Bimetallic Intermediate Formation
Sarakha,Ferraudi
, p. 313 - 317 (2008/10/09)
Flash photochemically generated Re(CO)5 reacts with halide complexes, Cu(Me4[14]-1,3,8,10-tetraeneN4)X+, Cu(Me2pyo[14]trieneN4)X+, and Ni(Me2pyo[14]trieneN4
