Synonyms:dimethyl 5-(3-methyl-1-phenyl-pyrazolyl)carbamate;pyrolan
99% *data from raw suppliers
Pyrolan *data from reagent suppliers
There total 1 articles about Pyrolan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
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The research focuses on the development of a method for the stereoselective synthesis of aryl C-glycosides using the Matsuda-Heck arylation of glycals. The study explores the use of various arene diazonium salts as coupling partners with a deoxygenated glycal synthesized from L-ethyl lactate through a tandem RCM-isomerization sequence. Key chemicals involved in this research include the MOM-protected glycal L-amicetal, which serves as the starting material, and a range of arene diazonium salts with different substituents (such as methoxy, fluorine, chlorine, bromine, and hydroxyl groups) that undergo the coupling reaction with the glycal under optimized conditions. The products obtained can be further functionalized through hydrogenation, epoxidation, or dihydroxylation to yield various derivatives, including 2,3,6-tridesoxy, 2,3-anhydro-6-desoxy, and 6-desoxy aryl C-glycosides. The method is also applied to the synthesis of an α-configured 6-desoxy-gliflozin derivative, highlighting its potential for creating complex aryl C-glycoside structures with high hydrolytic and metabolic stability.
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