Benzeneacetic acid, 2-chloro-.alpha.-(hydroxyMethylene)-, Methyl

Base Information

Chemical Name:Benzeneacetic acid, 2-chloro-.alpha.-(hydroxyMethylene)-, Methyl
CAS No.:83596-50-3
Molecular Formula:C10H9ClO3
Molecular Weight:212.633
Hs Code.:
Mol file:83596-50-3.mol

Synonyms:(Z)-METHYL 2-(2-CHLOROPHENYL)-3-HYDROXYACRYLATE;BENZENEACETIC ACID, 2-CHLORO-.ALPHA.-(HYDROXYMETHYLENE)-, METHYL ESTER;

Suppliers and Price of Benzeneacetic acid, 2-chloro-.alpha.-(hydroxyMethylene)-, Methyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Benzeneacetic acid, 2-chloro-.alpha.-(hydroxyMethylene)-, Methyl

Chemical Property:

PSA：46.53000
LogP:2.41190

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzeneacetic acid, 2-chloro-.alpha.-(hydroxyMethylene)-, Methyl

There total 1 articles about Benzeneacetic acid, 2-chloro-.alpha.-(hydroxyMethylene)-, Methyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 107-31-3
Methyl formate

: 57486-68-7
methyl (2-chlorophenyl)acetate

: 83596-50-3
methyl 2-(2-chlorophenyl)-3-hydroxyprop-2-enoate

Guidance literature:: Methyl formate; methyl (2-chlorophenyl)acetate; With titanium tetrachloride; triethylamine; In dichloromethane; at 0 - 25 ℃; Inert atmosphere;

With water; In dichloromethane;
DOI:10.1021/ol9013359

Reference yield: 92.0%

: 83596-50-3
methyl 2-(2-chlorophenyl)-3-hydroxyprop-2-enoate

: 98-59-9
p-toluenesulfonyl chloride

: 1188274-71-6
methyl (E)-2-(2-chlorophenyl)-3-(p-toluenesulfonyloxy)prop-2-enoate

Guidance literature:: With 1-methyl-1H-imidazole; triethylamine; In toluene; at 0 - 5 ℃; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol9013359

Reference yield:

: 83596-50-3
methyl 2-(2-chlorophenyl)-3-hydroxyprop-2-enoate

: 98-59-9
p-toluenesulfonyl chloride

: 1188274-71-6
methyl (E)-2-(2-chlorophenyl)-3-(p-toluenesulfonyloxy)prop-2-enoate

: 1188274-72-7
methyl (Z)-2-(2-chlorophenyl)-3-(p-toluenesulfonyloxy)prop-2-enoate

Guidance literature:: With 1-methyl-1H-imidazole; lithium hydroxide; In toluene; at 0 - 5 ℃; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol9013359