6,6-dichloro-2-Oxabicyclo[3.1.0]hexane

Base Information

• Chemical Name: 6,6-dichloro-2-Oxabicyclo[3.1.0]hexane
• CAS No.: 24765-58-0
• Molecular Formula: C₅H₆Cl₂O
• Molecular Weight: 153.008
• DSSTox Substance ID: DTXSID701283634
• Mol file: 24765-58-0.mol

Synonyms:6,6-dichloro-2-Oxabicyclo[3.1.0]hexane;24765-58-0;6,6-dichloro-2-oxa-bicyclo[3.1.0]hexane;DTXSID701283634;FT-0754269;2-Oxabicyclo[3.1.0]hexane, 6,6-dichloro-;A18522

Chemical Property of 6,6-dichloro-2-Oxabicyclo[3.1.0]hexane

Chemical Property:

• Boiling Point: 218.5±20.0 °C(Predicted)
• PSA: 9.23000
• Density: 1.45±0.1 g/cm3(Predicted)
• LogP: 1.57900
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 151.9795702
• Heavy Atom Count: 8
• Complexity: 124

Purity/Quality:

97% ^*data from raw suppliers

6,6-DICHLORO-2-OXABICYCLO[3.1.0]HEXANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1COC2C1C2(Cl)Cl

Technology Process of 6,6-dichloro-2-Oxabicyclo[3.1.0]hexane

There total 1 articles about 6,6-dichloro-2-Oxabicyclo[3.1.0]hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 6,6-Dichlor-2-oxabicyclo<3,1,0>hexan (24765-58-0)

Guidance literature:

2,3-Dihydrofuran, CCl2;

Reference yield: 31.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 6,6-dichloro-2-oxabicyclo<3.1.0>hexane (24765-58-0) → 1-chloro-1-phenylhexane (71434-68-9) + (6α,6aβ)-3,5,6,6a-Tetrahydro-6-phenyl-2H-cyclobutapyran (121029-48-9) + (6α,6aα)-3,5,6,6a-Tetrahydro-6-phenyl-2H-cyclobutapyran (121029-47-8)

Guidance literature:

With n-butyllithium; In hexane; Yields of byproduct given; 1.) -25 - -30 deg C, 1.5 h; 2.) to 0 deg C in 30 min;

Downstream raw materials:

1-chloro-1-phenylhexane

(6α,6aβ)-3,5,6,6a-Tetrahydro-6-phenyl-2H-cyclobutapyran

(6α,6aα)-3,5,6,6a-Tetrahydro-6-phenyl-2H-cyclobutapyran