Trifluoromethylthio-3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzene

Base Information

Chemical Name:Trifluoromethylthio-3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzene
CAS No.:1026796-07-5
Molecular Formula:C13H16BF3O2S
Molecular Weight:304.14
Hs Code.:2934999090
Mol file:1026796-07-5.mol

Synonyms:4,4,5,5-tetramethyl-2-[3-(trifluoromethylsulfanyl)phenyl]-1,3,2-dioxaborolane;

Suppliers and Price of Trifluoromethylthio-3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
4,4,5,5-Tetramethyl-2-(3-((trifluoromethyl)thio)phenyl)-1,3,2-dioxaborolane 95+%
1g
$ 1588.00

Total 5 raw suppliers

Chemical Property of Trifluoromethylthio-3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzene

Chemical Property:

PSA：43.76000
LogP:3.59770

Purity/Quality:

97% ^*data from raw suppliers

4,4,5,5-Tetramethyl-2-(3-((trifluoromethyl)thio)phenyl)-1,3,2-dioxaborolane 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Trifluoromethylthio-3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzene

There total 3 articles about Trifluoromethylthio-3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 456-56-4
phenyl trifluoromethylsulfide

: 73183-34-3
bis(pinacol)diborane

: 1005206-25-6
(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)(trifluoromethylsulfane)benzene

: 1026796-07-5
(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)(trifluoromethylsulfane)benzene

Guidance literature:: With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 5-phenyl-2,2’-bipyridine; In para-xylene; at 60 ℃; for 24h; Overall yield = 59 percent; Overall yield = 35.9 mg; regioselective reaction; Sealed tube;
DOI:10.1021/acs.orglett.0c00946

Reference yield:

: 456-56-4
phenyl trifluoromethylsulfide

: 73183-34-3
bis(pinacol)diborane

: 1005206-25-6
(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)(trifluoromethylsulfane)benzene

: 1026796-07-5
(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)(trifluoromethylsulfane)benzene

: C₁₉H₂₇B₂F₃O₄S

Guidance literature:: With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 4,4'-di-tert-butyl-2,2'-bipyridine; In cyclohexane; at 40 ℃; for 20h; Inert atmosphere;
DOI:10.1002/anie.201406424

Reference yield:

: 456-56-4
phenyl trifluoromethylsulfide

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1005206-25-6
(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)(trifluoromethylsulfane)benzene

: 1026796-07-5
(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)(trifluoromethylsulfane)benzene

Guidance literature:: With trans-carbonylchlorobis(trimethylphosphine)rhodium; for 8h; Overall yield = 75 %; Inert atmosphere; Glovebox; Irradiation; Schlenk technique; Sealed tube;
DOI:10.1039/c5ob01722j