2-(4-broMophenyl)-1,1,3,3-tetraMethyl-2,3-dihydro-1H-benzo[c][1,2,5]azadisilole

Base Information

Chemical Name:2-(4-broMophenyl)-1,1,3,3-tetraMethyl-2,3-dihydro-1H-benzo[c][1,2,5]azadisilole
CAS No.:132273-13-3
Molecular Formula:C₁₆H₂₀BrNSi₂
Molecular Weight:362.416
Hs Code.:
Mol file:132273-13-3.mol

Synonyms:2-(4-broMophenyl)-1,1,3,3-tetraMethyl-2,3-dihydro-1H-benzo[c][1,2,5]azadisilole

Suppliers and Price of 2-(4-broMophenyl)-1,1,3,3-tetraMethyl-2,3-dihydro-1H-benzo[c][1,2,5]azadisilole

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(4-broMophenyl)-1,1,3,3-tetraMethyl-2,3-dihydro-1H-benzo[c][1,2,5]azadisilole

Chemical Property:

PSA：3.24000
LogP:3.85850

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of 2-(4-broMophenyl)-1,1,3,3-tetraMethyl-2,3-dihydro-1H-benzo[c][1,2,5]azadisilole

There total 1 articles about 2-(4-broMophenyl)-1,1,3,3-tetraMethyl-2,3-dihydro-1H-benzo[c][1,2,5]azadisilole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 17985-72-7
1,2-bis(dimethylsilyl)benzene

: 106-40-1
4-bromo-aniline

: 132273-13-3
2-(4-Bromo-phenyl)-1,1,3,3-tetramethyl-2,3-dihydro-1H-benzo[1,2,5]azadisilole

Guidance literature:: cesium fluoride; In N,N,N,N,N,N-hexamethylphosphoric triamide; at 120 ℃; for 3.5h; other anilines;
DOI:10.1016/S0040-4039(00)97157-0

Reference yield:

: 132273-13-3
2-(4-Bromo-phenyl)-1,1,3,3-tetramethyl-2,3-dihydro-1H-benzo[1,2,5]azadisilole

: 132273-22-4
C₄₇H₅₄F₃NO₇

Guidance literature:: Multi-step reaction with 2 steps

1: 1) Li, 2) ZnBr₂ / 2) Pd(PPh₃)4 / 1) Et₂O, 2) THF

2: 1) H₂ / Pd/C / 1) EtOAc, 2) CHCl₃

With hydrogen; lithium; zinc dibromide; palladium on activated charcoal; tetrakis(triphenylphosphine) palladium⁽⁰⁾;
DOI:10.1016/S0040-4039(00)97157-0

Reference yield:

: 132273-13-3
2-(4-Bromo-phenyl)-1,1,3,3-tetramethyl-2,3-dihydro-1H-benzo[1,2,5]azadisilole

: 132273-20-2
C₄₀H₄₇F₃O₉S

: 132273-21-3
C₅₅H₆₇NO₆Si₂

Guidance literature:: With lithium; zinc dibromide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Yield given. Multistep reaction; 1) Et₂O, 2) THF;
DOI:10.1016/S0040-4039(00)97157-0