sodium;1H-indazole;ruthenium(3+);tetrachloride

Base Information

• Chemical Name: sodium;1H-indazole;ruthenium(3+);tetrachloride
• CAS No.: 197723-00-5
• Molecular Formula: C14H12Cl4N4Ru.Na
• Molecular Weight: 502.14365
• UNII: 7OSJ9KS483
• Mol file: 197723-00-5.mol

Synonyms:sodium;1H-indazole;ruthenium(3+);tetrachloride;RUTHENATE(1-), TETRACHLOROBIS(1H-INDAZOLE-.KAPPA.N2)-, SODIUM (1:1), (OC-6-11)-

Chemical Property of sodium;1H-indazole;ruthenium(3+);tetrachloride

Chemical Property:

• PSA: 71.76000
• LogP: 1.54010
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 502.872767
• Heavy Atom Count: 24
• Complexity: 103

Purity/Quality:

97% ^*data from raw suppliers

NKP-1339 >98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=NN2.C1=CC=C2C(=C1)C=NN2.[Na+].[Cl-].[Cl-].[Cl-].[Cl-].[Ru+3]

Technology Process of sodium;1H-indazole;ruthenium(3+);tetrachloride

There total 6 articles about sodium;1H-indazole;ruthenium(3+);tetrachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tetraphenylphosphonium trans-tetrachlorobis(indazole)ruthenate(III) (197722-94-4) + sodium tetraphenyl borate (143-66-8) → sodium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] (197723-00-5)

Guidance literature:

In acetonitrile; byproducts: [P(C6H5)4][B(C6H5)4]; stirring (5 min); filtration, pptn. (Et2O, 4°C, 30 min), filtration, drying (vacuum, P2O5); elem. anal.;

DOI:10.1002/(sici)1099-0682(199909)1999:9<1551::aid-ejic1551>3.0.co;2-7

Reference yield: 41.0%

1H-indazolium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] (124875-20-3,142388-45-2) → sodium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] (197723-00-5)

Guidance literature:

With sodium dihydrogen phosphate monohydrate; In water; acetone;

Reference yield:

cesium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] dihydrate + sodium sulfate (7757-82-6) → sodium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] (197723-00-5)

Guidance literature:

sodium sulfate; With aluminum(III) sulphate octadecahydrate; In water; at 20 ℃; for 0.5h;

cesium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] dihydrate; With cesium chloride; In water; at 20 ℃; for 30h;

upstream raw materials:

tetramethylammonium trans-tetrachlorobis(indazole)ruthenate(III)

sodium tetraphenyl borate

tetraphenylphosphonium trans-tetrachlorobis(indazole)ruthenate(III)

tetra(n-butyl)ammonium trans-tetrachlorobis(indazole)ruthenate(III)