5-Thio-D-glucopyranose 1,2,3,4,6-pentaacetate

Base Information

Chemical Name:5-Thio-D-glucopyranose 1,2,3,4,6-pentaacetate
CAS No.:10470-80-1
Molecular Formula:C16H22O10S
Molecular Weight:406.4
Hs Code.:
Mol file:10470-80-1.mol

Synonyms:1,2,3,4,6-penta-O-acetyl-5-thio-D-glucopyranose;.Penta-O-acetyl-5-thio-D-glucopyranose;

Suppliers and Price of 5-Thio-D-glucopyranose 1,2,3,4,6-pentaacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 12 raw suppliers

Chemical Property of 5-Thio-D-glucopyranose 1,2,3,4,6-pentaacetate

Chemical Property:

PSA：156.80000
LogP:0.34920

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 5-Thio-D-glucopyranose 1,2,3,4,6-pentaacetate

There total 16 articles about 5-Thio-D-glucopyranose 1,2,3,4,6-pentaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.1%

: 16505-91-2
(3R,4S,5S,6R)-6-(hydroxymethyl)tetrahydro-2H-thiopyran-2,3,4,5-tetraol

: 108-24-7
acetic anhydride

: 10470-80-1
1,2,3,4,6-penta-O-acetyl-5-thio-α,β-D-glucopyranose

Guidance literature:: With pyridine; dmap; at 0 - 20 ℃; for 12h;

Reference yield: 60.0%

: 10227-17-5
3,6-di-O-acetyl-5-S-acetyl-6-O-acetyl-1,2-O-isopropylidene-α-D-glucofuranose

: 108-24-7
acetic anhydride

: 10470-80-1
1,2,3,4,6-penta-O-acetyl-5-thio-α,β-D-glucopyranose

Guidance literature:: 3,6-di-O-acetyl-5-S-acetyl-6-O-acetyl-1,2-O-isopropylidene-α-D-glucofuranose; With acetic acid; at 90 ℃; for 12h; Inert atmosphere;

With sodium methylate; at 0 ℃; for 4h; Inert atmosphere;

acetic anhydride; With pyridine; at 20 ℃; for 12h; Inert atmosphere;
DOI:10.1021/acs.joc.8b01645

Reference yield:

: 108-24-7
acetic anhydride

: 2,3,4,6-Tetra-O-benzoyl-5-thio-D-glucopyranose

: 10470-80-1
1,2,3,4,6-penta-O-acetyl-5-thio-α,β-D-glucopyranose

Guidance literature:: 2,3,4,6-Tetra-O-benzoyl-5-thio-D-glucopyranose; With sodium methylate; In methanol; at 20 ℃; for 1h;

acetic anhydride; With pyridine; dmap; In tetrahydrofuran; for 6h;