alpha-D-Glucopyranose, 5-thio-, 1,2,3,4,6-pentaacetate

Base Information

Chemical Name:alpha-D-Glucopyranose, 5-thio-, 1,2,3,4,6-pentaacetate
CAS No.:10227-18-6
Molecular Formula:C16H22 O10 S
Molecular Weight:406.40488
Hs Code.:
DSSTox Substance ID:DTXSID001242267
Nikkaji Number:J352.534A
Mol file:10227-18-6.mol

Synonyms:alpha-D-Glucopyranose, 5-thio-, 1,2,3,4,6-pentaacetate;DTXSID001242267;penta-O-acetyl-5-thio-alpha-d-glucopyranose;5-Thio-alpha-D-glucopyranose 1,2,3,4,6-pentaacetate;[(2R,3S,4S,5R,6S)-3,4,5,6-tetraacetyloxythian-2-yl]methyl acetate

Suppliers and Price of alpha-D-Glucopyranose, 5-thio-, 1,2,3,4,6-pentaacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Medical Isotopes, Inc.
1-2-3-4-6-Penta-O-acetyl-5-thio-α-D-glucopyranose
25 mg
$ 550.00

Biosynth Carbosynth
1,2,3,4,6-Penta-O-acetyl-5-thio-a-D-glucopyranose
50 mg
$ 3250.00

Biosynth Carbosynth
1,2,3,4,6-Penta-O-acetyl-5-thio-a-D-glucopyranose
25 mg
$ 2500.00

American Custom Chemicals Corporation
PENTAACETYL-5-THIOGLUCOSE 95.00%
5G
$ 912.29

American Custom Chemicals Corporation
PENTAACETYL-5-THIOGLUCOSE 95.00%
2.5G
$ 796.77

American Custom Chemicals Corporation
PENTAACETYL-5-THIOGLUCOSE 95.00%
1G
$ 619.70

Total 12 raw suppliers

Chemical Property of alpha-D-Glucopyranose, 5-thio-, 1,2,3,4,6-pentaacetate

Chemical Property:

PSA：52.60000
LogP:-0.66420
XLogP3:0.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:11
Rotatable Bond Count:11
Exact Mass:406.09336807
Heavy Atom Count:27
Complexity:604

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-2-3-4-6-Penta-O-acetyl-5-thio-α-D-glucopyranose ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C(C(S1)OC(=O)C)OC(=O)C)OC(=O)C)OC(=O)C
Isomeric SMILES:CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@H](S1)OC(=O)C)OC(=O)C)OC(=O)C)OC(=O)C

Technology Process of alpha-D-Glucopyranose, 5-thio-, 1,2,3,4,6-pentaacetate

There total 7 articles about alpha-D-Glucopyranose, 5-thio-, 1,2,3,4,6-pentaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

: 153053-29-3
phenyl 2,3,4,6-tetra-O-acetyl-1,5-dithio-β-D-glucopyranoside

: 176213-92-6
1,6-anhydro-2-azido-3-O-(tert-butyldimethylsilyl)-2-deoxy-β-D-glucopyranose

: C₆H₇S(OCOCH₃)4OC₁₂H₂₂N₃O₃Si

: 10227-18-6
1,2,3,4,6-penta-O-acetyl-5-thio-α-D-glucopyranoside

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; In 1,2-dichloro-ethane; at -20 ℃; for 1h;
DOI:10.1016/j.tetlet.2007.09.056

Reference yield:

: 10470-80-1
1,2,3,4,6-penta-O-acetyl-5-thio-α,β-D-glucopyranose

: 10227-18-6
1,2,3,4,6-penta-O-acetyl-5-thio-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 30 percent HBr / CH₂Cl₂; acetic acid / 24 h / 0 °C

2: silver acetate / benzene / 1 h / Heating

With hydrogen bromide; silver(I) acetate; In dichloromethane; acetic acid; benzene;
DOI:10.1016/S0008-6215(00)81800-5

Reference yield:

: 84039-44-1
2,3,4,6-tetra-O-acetyl-5-thio-α-D-glucopyranosyl bromide

: 10227-18-6
1,2,3,4,6-penta-O-acetyl-5-thio-α-D-glucopyranoside

: 35827-66-8
1,2,3,4,6-penta-O-acetyl-5-thio-β-D-glucopyranose

Guidance literature:: With silver(I) acetate; In benzene; for 1h; Yield given. Yields of byproduct given; Heating;
DOI:10.1016/S0008-6215(00)81800-5