meso-Tetrakis(4-chlorophenyl)porphyrin-Fe(III)chloride

Base Information

• Chemical Name: meso-Tetrakis(4-chlorophenyl)porphyrin-Fe(III)chloride
• CAS No.: 36965-70-5
• Molecular Formula: C44H24Cl5FeN4
• Molecular Weight: 841.813
• Mol file: 36965-70-5.mol

Synonyms:5,10,15,20-tetrakis(p-chlorophenyl)porphyrin iron(III) chloride;chloro[meso-tetrakis(p-chlorophenyl)porphyrinato]iron(III);5,10,15,20-tetra(p-chlorophenyl)porphyrin iron(III) chloride;

Chemical Property of meso-Tetrakis(4-chlorophenyl)porphyrin-Fe(III)chloride

Chemical Property:

• PSA: 15.88000
• LogP: 9.73840
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98.5% ^*data from raw suppliers

5,10,15,20-tetrakis(p-chlorophenyl)porphyriniron(III)chloride 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of meso-Tetrakis(4-chlorophenyl)porphyrin-Fe(III)chloride

There total 6 articles about meso-Tetrakis(4-chlorophenyl)porphyrin-Fe(III)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.4%

5,10,15,20-tetra-(4-chlorophenyl)porphyrin (22112-77-2) → 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin iron(III) chloride (36965-70-5)

Guidance literature:

5,10,15,20-tetra-(4-chlorophenyl)porphyrin; With iron(II) chloride tetrahydrate; In N,N-dimethyl-formamide; for 0.5h;

With hydrogenchloride; In water; at 50 - 60 ℃;

DOI:10.3390/molecules16042960

Reference yield: 99.4%

iron(II) chloride tetrahydrate + 5,10,15,20-tetra-(4-chlorophenyl)porphyrin (22112-77-2) → 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin iron(III) chloride (36965-70-5)

Guidance literature:

In N,N-dimethyl-formamide; for 0.5h; Reflux;

DOI:10.1021/op060056z

Reference yield: 90.0%

5,10,15,20-tetrakis(4-chlorophenyl)porphyrin + iron(II) chloride → 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin iron(III) chloride (36965-70-5)

Guidance literature:

With water; In N,N-dimethyl-formamide; tetra(p-chlorophenyl)porphin refluxed in DMF with stirring and then FeCl2 added; mixt. cooled to room temp. and water added into react. mixt.; ppt. collected by filtration, washed with warm water, abs. ethanol and dried in vac.; compd. purified by column chromy. (silica gel petrolium ether/chloroform); elem. anal.;

DOI:10.1016/j.molcata.2008.01.040

upstream raw materials:

pyrrole

4-chlorobenzaldehyde

5,10,15,20-tetra-(4-chlorophenyl)porphyrin

Downstream raw materials:

chloride

iron(III)

[T(p-Cl)PPFeCl]₂O

iron(II) tetrakis(p-chlorophenyl)porphyrin thiocarbonyl

Refernces

• 1、 Xu, Weijie,Fang, Yuanyuan,Ou, Zhongping,Chen, Mingyuan,Kadish, Karl M.. "Synthesis, electrochemical and spectroelectrochemical characterization of iron(III) tetraarylporphyrins containing four β, β ′-butano and β, β ′-benzo fused rings". . p. 521 - 534. Retrieved 2018/05/14.
• 2、 -. "A preparing method of p-nitroacetophenone". Paragraph 0042-0044. . Retrieved 2019/01/07.