meso-Tetrakis(4-chlorophenyl)porphyrin-Co(II)

Base Information

• Chemical Name: meso-Tetrakis(4-chlorophenyl)porphyrin-Co(II)
• CAS No.: 55915-17-8
• Molecular Formula: C44H24Cl4CoN4
• Molecular Weight: 809.507
• Mol file: 55915-17-8.mol

Synonyms:Co(5,10,15,20-tetrakis(4-chlorophenyl)porphyrin);cobalt(II) 5,10,15,20-tetra(4'-chlorophenyl)porphyrinate;T(p-Cl)PPCo;Co(II)(meso-tetrakis(4-chlorophenyl)porphyrin);CoTClPPCl;Tetra (4-chlorophenyl) porphinatocobalt;cobalt tetra(para-chlorophenyl)porphyrin;

Chemical Property of meso-Tetrakis(4-chlorophenyl)porphyrin-Co(II)

Chemical Property:

• PSA: 15.88000
• LogP: 9.05140

Purity/Quality:

98.5% ^*data from raw suppliers

5,10,15,20-Tetrakis(p-chlorophenyl)porphyrinatocobalt(II) 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of meso-Tetrakis(4-chlorophenyl)porphyrin-Co(II)

There total 8 articles about meso-Tetrakis(4-chlorophenyl)porphyrin-Co(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

cobalt(II) acetate dihydrate + 5,10,15,20-tetra-(4-chlorophenyl)porphyrin (22112-77-2) → 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin cobalt (II) (55915-17-8)

Guidance literature:

In methanol; chloroform; at 20 ℃; for 2h;

DOI:10.1021/acs.inorgchem.7b02405

Reference yield: 77.0%

cobalt(II) acetate (71-48-7,917-69-1,5931-89-5,55881-15-7,68931-68-0,68931-69-1,93029-27-7) + 5,10,15,20-tetra-(4-chlorophenyl)porphyrin (22112-77-2) → 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin cobalt (II) (55915-17-8)

Guidance literature:

In N,N-dimethyl-formamide; for 0.00833333h; Reflux;

DOI:10.1134/S1070363219030150

Reference yield: 60.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + 5,10,15,20-tetra-(4-chlorophenyl)porphyrin (22112-77-2) → 5,10,15,20-tetrakis(p-chlorophenyl)porphyrin cobalt (II) (55915-17-8)

Guidance literature:

With aluminum oxide; lithium hydroxide; for 0.833333h; Milling; Green chemistry;

DOI:10.1039/d0gc01010c

upstream raw materials:

cobalt(II) acetate

5,10,15,20-tetra-(4-chlorophenyl)porphyrin

4-chlorobenzaldehyde

dicobalt octacarbonyl

Downstream raw materials:

C₅₀H₂₉Cl₄CoN₄

(meso-5,10,15,20-tetra-p-Cl-phenylporphine)cobalt(III)Br

[(meso-5,10,15,20-tetra-p-Cl-phenylporphine)cobalt(III)I]

Refernces

• 1、 Shen, Hai-Min,Wang, Xiong,Ning, Lei,Guo, A-Bing,Deng, Jin-Hui,She, Yuan-Bin. "Efficient oxidation of cycloalkanes with simultaneously increased conversion and selectivity using O2 catalyzed by metalloporphyrins and boosted by Zn(AcO)2: A practical strategy to inhibit the formation of aliphatic diacids". . . Retrieved 2020/11/20.
• 2、 Guergueb, Mouhieddinne,Nasri, Soumaya,Brahmi, Jihed,Al-Ghamdi, Youssef O.,Loiseau, Frédérique,Molton, Florian,Roisnel, Thierry,Guerineau, Vincent,Nasri, Habib. "Spectroscopic characterization, X-ray molecular structures and cyclic voltammetry study of two (piperazine) cobalt(II) meso-arylporphyin complexes. Application as a catalyst for the degradation of 4-nitrophenol". . . Retrieved 2021/10/01.