6,6'-Dinitro[1,1'-biphenyl]-2,2'-diamine

Base Information

Chemical Name:6,6'-Dinitro[1,1'-biphenyl]-2,2'-diamine
CAS No.:54147-72-7
Molecular Formula:C₁₂H₁₀N₄O₄
Molecular Weight:274.236
Hs Code.:2921590090
DSSTox Substance ID:DTXSID40701529
Nikkaji Number:J89.846E
Wikidata:Q82633225
Mol file:54147-72-7.mol

Synonyms:54147-72-7;DTXSID40701529;6,6'-Dinitrobiphenyl-2,2'-diamine;6,6'-Dinitro[1,1'-biphenyl]-2,2'-diamine

Suppliers and Price of 6,6'-Dinitro[1,1'-biphenyl]-2,2'-diamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 6,6'-Dinitro[1,1'-biphenyl]-2,2'-diamine

Chemical Property:

PSA：143.68000
LogP:4.54320
XLogP3:1.8
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:1
Exact Mass:274.07020481
Heavy Atom Count:20
Complexity:345

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=C(C(=C1)[N+](=O)[O-])C2=C(C=CC=C2[N+](=O)[O-])N)N

Technology Process of 6,6'-Dinitro[1,1'-biphenyl]-2,2'-diamine

There total 6 articles about 6,6'-Dinitro[1,1'-biphenyl]-2,2'-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 95515-30-3
6,6′-dinitro[1,1′-biphenyl]-2,2′-dicarboxamide

: 54147-72-7
6,6′-dinitro[1,1′-biphenyl]-2,2′-diamine

Guidance literature:: With bromine; sodium hydroxide; In water; at 0 - 90 ℃; for 0.416667h;
DOI:10.1021/acs.joc.7b00079

Reference yield:

: 5457-32-9,50573-78-9,50573-79-0
6,6'-dinitro-2,2'-dicarboxybiphenyl

: 54147-72-7
6,6′-dinitro[1,1′-biphenyl]-2,2′-diamine

Guidance literature:: Multi-step reaction with 3 steps

1: dmap; thionyl chloride / 2 h / Reflux; Inert atmosphere

2: ammonium hydroxide / 1,4-dioxane / 12 h / 25 °C

3: bromine; sodium hydroxide / water / 0.42 h / 0 - 90 °C

With dmap; ammonium hydroxide; thionyl chloride; bromine; sodium hydroxide; In 1,4-dioxane; water;
DOI:10.1021/acs.joc.7b00079

Reference yield:

: 55153-02-1
2,2'-dinitro-6,6'-dimethyl-1,1'-biphenyl

: 54147-72-7
6,6′-dinitro[1,1′-biphenyl]-2,2′-diamine

Guidance literature:: Multi-step reaction with 4 steps

1: sulfuric acid; sodium dichromate; acetic acid / water / 4 h / Reflux

2: dmap; thionyl chloride / 2 h / Reflux; Inert atmosphere

3: ammonium hydroxide / 1,4-dioxane / 12 h / 25 °C

4: bromine; sodium hydroxide / water / 0.42 h / 0 - 90 °C

With dmap; ammonium hydroxide; thionyl chloride; sodium dichromate; sulfuric acid; bromine; acetic acid; sodium hydroxide; In 1,4-dioxane; water;
DOI:10.1021/acs.joc.7b00079