2,2'-Dinitro-6,6'-dimethylbiphenyl

Base Information

• Chemical Name: 2,2'-Dinitro-6,6'-dimethylbiphenyl
• CAS No.: 55153-02-1
• Molecular Formula: C14H12N2O4
• Molecular Weight: 272.26
• NSC Number: 159238
• DSSTox Substance ID: DTXSID30303591
• Nikkaji Number: J1.277.303J
• Wikidata: Q82048951
• Mol file: 55153-02-1.mol

Synonyms:2,2'-dinitro-6,6'-dimethylbiphenyl;55153-02-1;1,1'-Biphenyl, 2,2'-dimethyl-6,6'-dinitro-;2,2'-Dimethyl-6,6'-dinitro-1,1'-biphenyl;NSC159238;Oprea1_014758;SCHEMBL6051840;1-methyl-2-(2-methyl-6-nitro-phenyl)-3-nitro-benzene;DTXSID30303591;2,8-dinitro-6,12-dimethyl biphenyl;AKOS024262810;CCG-233782;NSC-159238;2,2'-Dimethyl-6,6'-dinitro-diphenyl;6,6'-dimethyl-2,2'-dinitro-1,1'-biphenyl;2,2'-Dimethyl-6,6'-dinitro-1,1'-biphenyl #;A830717

Chemical Property of 2,2'-Dinitro-6,6'-dimethylbiphenyl

Chemical Property:

• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 272.07970687
• Heavy Atom Count: 20
• Complexity: 340

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=C(C(=CC=C1)[N+](=O)[O-])C2=C(C=CC=C2[N+](=O)[O-])C

Technology Process of 2,2'-Dinitro-6,6'-dimethylbiphenyl

There total 5 articles about 2,2'-Dinitro-6,6'-dimethylbiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

2-Methyl-6-nitroaniline (570-24-1) + 2-iodo-3-nitrotoluene (6277-17-4) → 2,2'-dinitro-6,6'-dimethyl-1,1'-biphenyl (55153-02-1) + bis(2-methyl-6-nitrophenyl)amine (155652-89-4)

Guidance literature:

With copper; at 140 ℃; for 2h;

Reference yield:

→ 2,2'-dinitro-6,6'-dimethyl-1,1'-biphenyl (55153-02-1) + 2-chloro-3-nitrotoluene (3970-40-9)

Guidance literature:

With hydrogenchloride; copper dichloride;

Reference yield:

→ 2,2'-dinitro-6,6'-dimethyl-1,1'-biphenyl (55153-02-1) + 2,2'-dimethyl-6,6'-dinitroazobenzene (109670-19-1)

Guidance literature:

With hydroxylamine hydrochloride; ammonia; water; copper(II) sulfate;

DOI:10.1021/ja01259a064

upstream raw materials:

2-Methyl-6-nitroaniline

2-iodo-3-nitrotoluene

Downstream raw materials:

(S)-6,6'-dimethyl-2,2'-diaminobiphenyl

(Ra)-6,6'-dimethyl-1,1'-biphenyl-2,2'-diamine

6,6′-dinitro[1,1′-biphenyl]-2,2′-diamine

9,10-dihydrophenanthrene