1-Bromovinylboronic acid MIDA ester

Base Information

Chemical Name:1-Bromovinylboronic acid MIDA ester
CAS No.:1449377-16-5
Molecular Formula:
Molecular Weight:261.868
Hs Code.:
Mol file:1449377-16-5.mol

Synonyms:1-Bromovinylboronic acid MIDA ester;1-Bromovinyl-1-boronic acid MIDA ester;1-Bromovinyl-1-boronic acid MIDA ester 95%

Suppliers and Price of 1-Bromovinylboronic acid MIDA ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of 1-Bromovinylboronic acid MIDA ester

Chemical Property:

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-Bromovinylboronic acid MIDA ester

There total 2 articles about 1-Bromovinylboronic acid MIDA ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 1104636-73-8
6-methyl-2-vinyl-1,3,6,2-dioxazaborocane-4,8-dione

: 1449377-16-5
C₇H₉BBrNO₄

Guidance literature:: 6-methyl-2-vinyl-1,3,6,2-dioxazaborocane-4,8-dione; With bromine; In dichloromethane; at 0 - 23 ℃; for 0.583333h; Inert atmosphere;

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In acetonitrile; at 23 ℃; for 1h; Inert atmosphere;
DOI:10.1016/j.tet.2013.05.050

Reference yield:

: 4408-64-4
N-methyliminodiacetic acid

: 1449377-16-5
C₇H₉BBrNO₄

Guidance literature:: Multi-step reaction with 2 steps

1.1: Trimethyl borate / tetrahydrofuran / 5.5 h / -78 - 23 °C / Inert atmosphere

1.2: 2.17 h / 105 - 115 °C / Inert atmosphere

2.1: bromine / dichloromethane / 0.58 h / 0 - 23 °C / Inert atmosphere

2.2: 1 h / 23 °C / Inert atmosphere

With Trimethyl borate; bromine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tet.2013.05.050

Reference yield: 90.0%

: 1449377-16-5
C₇H₉BBrNO₄

: 17933-03-8
m-tolylboronic acid

: 1449377-18-7
C₁₄H₁₆BNO₄

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 1,6-bis(diphenylphosphino)hexane; silver carbonate; In tetrahydrofuran; at 40 ℃; for 24h; Sealed tube; Inert atmosphere;
DOI:10.1016/j.tet.2013.05.050