Phenyl 2-azido-2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

Base Information

Chemical Name:Phenyl 2-azido-2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside
CAS No.:236115-65-4
Molecular Formula:C33H33N3O4S
Molecular Weight:567.709
Hs Code.:

Synonyms:Phenyl 2-azido-2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

Suppliers and Price of Phenyl 2-azido-2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of Phenyl 2-azido-2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

Chemical Property:

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Phenyl 2-azido-2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside

There total 5 articles about Phenyl 2-azido-2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-beta-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 929040-77-7,501088-45-5
4-methylphenyl 3,4,6-tri-O-acetyl-2-azido-2-deoxy-1-thio-α,β-D-glucopyranoside

: 100-39-0
benzyl bromide

: C₄₂H₄₅N₃O₄SSi

: 236115-65-4
2-azido-2-deoxy-3,4,6-tri-O-benzyl-1-phenylthio-β-D-glucopyranoside

: (2R,3R,4R,5S,6R)-3-Azido-4,5-bis-benzyloxy-6-benzyloxymethyl-2-phenylsulfanyl-tetrahydro-pyran

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 2h; Inert atmosphere;
DOI:10.1016/j.carres.2016.03.021

Reference yield: 60.0%

: 100-39-0
benzyl bromide

: 166516-67-2
phenyl 2-azido-2-deoxy-1-thio-β-D-glucopyranoside

: 236115-65-4
2-azido-2-deoxy-3,4,6-tri-O-benzyl-1-phenylthio-β-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 2h;
DOI:10.1021/ja9910356

Reference yield: 37.0%

: 100-39-0
benzyl bromide

: 166516-67-2
phenyl 2-azido-2-deoxy-1-thio-β-D-glucopyranoside

: phenyl 2-azido-4,6-di-O-benzyl-2-deoxy-1-thio-β-D-glucopyranoside

: 801300-72-1
phenyl 2-azido-3,4-di-O-benzyl-2-deoxy-1-thio-β-D-glucopyranoside

: 236115-65-4
2-azido-2-deoxy-3,4,6-tri-O-benzyl-1-phenylthio-β-D-glucopyranoside

: 277756-87-3
phenyl 2-azido-3,6-di-O-benzyl-2-deoxy-1-thio-β-D-glucopyranoside

Guidance literature:: With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane; water; at 50 ℃; for 15h; Further byproducts given;
DOI:10.1081/CAR-200053712