2,5-Dimethoxy-beta-oxobenzenepropanoic acid methyl ester

Base Information

Chemical Name:2,5-Dimethoxy-beta-oxobenzenepropanoic acid methyl ester
CAS No.:1225553-37-6
Molecular Formula:C₁₂H₁₄O₅
Molecular Weight:238.24
Hs Code.:2918990090
Mol file:1225553-37-6.mol

Synonyms:2,5-Dimethoxy-beta-oxobenzenepropanoic acid methyl ester;Methyl 3-(2,5-diMethoxyphenyl)-3-oxopropanoate

Suppliers and Price of 2,5-Dimethoxy-beta-oxobenzenepropanoic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl3-(2,5-Dimethoxyphenyl)-3-oxopropanoate
100mg
$ 175.00

Alichem
Methyl3-(2,5-dimethoxyphenyl)-3-oxopropanoate
1g
$ 400.00

AK Scientific
Methyl3-(2,5-Dimethoxyphenyl)-3-Oxopropanoate
100mg
$ 178.40

Total 8 raw suppliers

Chemical Property of 2,5-Dimethoxy-beta-oxobenzenepropanoic acid methyl ester

Chemical Property:

Boiling Point:333℃
Flash Point:168℃
PSA：61.83000
Density:1.159
LogP:1.44960
Storage Temp.:2-8°C

Purity/Quality:

98%min ^*data from raw suppliers

Methyl3-(2,5-Dimethoxyphenyl)-3-oxopropanoate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,5-Dimethoxy-beta-oxobenzenepropanoic acid methyl ester

There total 1 articles about 2,5-Dimethoxy-beta-oxobenzenepropanoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1201-38-3
2',5'-dimethoxyacetophenone

: 1225553-37-6
methyl 3-(2,5-dimethoxyphenyl)-3-oxopropanoate

Guidance literature:: With sodium hydride; In toluene; paraffin oil; at 20 - 110 ℃; for 1.5h; Inert atmosphere;
DOI:10.1002/anie.201712141

Reference yield: 3.0%

: 43161-11-1
5-iodo-2-methylpent-2-ene

: 1225553-37-6
methyl 3-(2,5-dimethoxyphenyl)-3-oxopropanoate

: methyl 2-(2,5-dimethoxybenzoyl)-6-methylhept-5-enoate

Guidance literature:: methyl 3-(2,5-dimethoxyphenyl)-3-oxopropanoate; With sodium hydride; In tetrahydrofuran; paraffin oil; at 0 ℃; for 0.166667h; Inert atmosphere;

5-iodo-2-methylpent-2-ene; In tetrahydrofuran; paraffin oil; at 55 ℃; for 16h; Inert atmosphere;
DOI:10.1002/anie.201712141

Reference yield:

: 1225553-37-6
methyl 3-(2,5-dimethoxyphenyl)-3-oxopropanoate

: methyl 2-(2,5-dimethoxyphenyl)cyclopent-2-ene-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / paraffin oil; tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

1.2: 16 h / 55 °C / Inert atmosphere

2.1: C-undecyl resorcin[4]arene; hydrogenchloride / water; chloroform / 26 h / 50 °C / Sealed tube

With hydrogenchloride; C-undecyl resorcin[4]arene; sodium hydride; In tetrahydrofuran; chloroform; water; paraffin oil; 2.1: |Alkene (Olefin) Metathesis;
DOI:10.1002/anie.201712141